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106550

Sigma-Aldrich

内消旋-1,2-二溴-1,2-二苯基乙烷

≥97%

别名:

1,2-二溴-1,2-联苯乙烷

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About This Item

线性分子式:
C6H5CH(Br)CH(Br)C6H5
CAS号:
13440-24-9
分子量:
340.05
MDL编号:
MFCD00085299
UNSPSC代码:
12352100
PubChem化学物质编号:
24846737
NACRES:
NA.22
价格与库存信息目前不能提供

方案

≥97%

表单

solid

mp

241 °C (dec.) (lit.)

官能团

bromo
phenyl

SMILES字符串

Br[C@H]([C@H](Br)c1ccccc1)c2ccccc2

InChI

1S/C14H12Br2/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10,13-14H/t13-,14+

InChI key

GKESIQQTGWVOLH-OKILXGFUSA-N

相关类别

一般描述

meso-1,2-Dibromo-1,2-diphenylethane undergoes electrochemical dehalogenation in acetonitrile[1]. It is reduced by electrogenerated C60−3[2].

应用

meso-1,2-Dibromo-1,2-diphenylethane(meso-SBr2) was used to study the reaction of ± and meso-SBr2 with 9-substituted fluorenide ions in dimethyl sulfoxide[3].

象形图

CorrosionExclamation mark
GHS05,GHS07

警示用语：

Danger

危险声明

H302,H314

危险分类

Acute Tox. 4 Oral - Skin Corr. 1B

储存分类代码

8A - Combustible corrosive hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCK4320
STBJ2118
STBG1139V
STBF0433V
STBD2091V

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Debromination of meso-and (?)-1, 2-Dibromo-1, 2-diphenylethane by 9-Substituted Fluorenide Ions: Correlation between Stereochemical Results and Redox Potentials.
Lund T, et al.
Acta Chemica Scandinavica, 47, 877-877 (1993)
Electro-organic chemistry of fullerenes. Part 1. Indirect cathodic reduction of vic-dihalides and perfluoroalkyl halides using C60 as mediator. Cyclic voltammetric study and preparative-scale electrolysis.
Fuchigami T, et al.
Journal of Electroanalytical Chemistry, 411(1), 115-119 (1996)
Reduction of Vicinal Dihalides. I. The Electrochemical Reduction of meso and (?)-1, 2-Dibromo-1, 2-diphenylethane.
Fawell P, et al.
Australian Journal of Chemistry, 43(8), 1421-1430 (1990)

Questions

1–6 of 6 Questions  

  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  3. Where can I find product similar to meso-1,2-Dibromo-1,2-diphenylethane offered by Sigma-Aldrich?

    1 answer

    1. The Sigma-Aldrich website provides many resources for locating products with similar structural characteristics. At the bottom of the product information page for product 106550, there are links to "Related Categories". These links including listings of Sigma-Aldrich products that fall in the same category as meso-1,2-Dibromo-1,2-diphenylethane. Alternatively, Sigma-Aldrich offers an online catalog that provides organized listings of products useful for chemical synthesis, grouped by similar characteristics.

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  4. What is the Department of Transportation shipping information for this product?

    1 answer

    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

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  5. Is Stilbene dibromide, Product 106550, optically active?

    1 answer

    1. Generally, chiral molecules are optically active, rotating polarized light. Meso compounds, such as 106550, are unique in that there are chiral carbons in the molecule yet they are not optically active. meso-1,2-Dibromo-1,2-diphenylethane has chiral carbons that are virtually identical but the arrangement of the groups on this carbon are different; the result of these opposing effects is a net optical rotation of zero.

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  6. In what solvents is Stilbene dibromide, Product 106550, soluble?

    1 answer

    1. Sigma-Aldrich does not currently test this product for solubility in a particular solvent. However, our quality control does solubilize this product with acetonitrile (with sonication) for analysis by HPLC at a concentration of 0.5mg/mL.

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