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等级
derivatization grade ((chiral))
for chiral derivatization
质量水平
蒸汽压
0.5 mmHg ( 20 °C)
方案
≥99.0% (sum of enantiomers, GC)
≥99.0%
表单
liquid
旋光性
[α]20/D +30±1°, c = 10% in ethanol
光学纯度
enantiomeric ratio: ≥99.5:0.5 (GC)
质量
LiChropur™
技术
HPLC: suitable
折射率
n20/D 1.526 (lit.)
n20/D 1.528
沸点
187-189 °C (lit.)
密度
0.952 g/mL at 20 °C (lit.)
储存温度
2-8°C
SMILES字符串
C[C@@H](N)c1ccccc1
InChI
1S/C8H11N/c1-7(9)8-5-3-2-4-6-8/h2-7H,9H2,1H3/t7-/m1/s1
InChI key
RQEUFEKYXDPUSK-SSDOTTSWSA-N
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一般描述
(R)-(+)-α-Methylbenzylamine is a high quality, useful chiral derivatization reagent for all analytical applications, specific to GC in the chiral field. It is specially selected to meet the requirements for derivatization reagents for enantiomeric excess determinations.
应用
(R)-(+)-a-Methylbenzylamine also known as (R)-(+)-1-Phenylethylamine may be used in resolution of a chiral arylalkylamine involving high-conversion enantioselective condensation with capric acid followed by hydrolysis to yield corresponding (R)-(+)-amide.
其他说明
用于测定酸对映体纯度的手性胺
法律信息
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany
警示用语:
Danger
危险声明
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 1
闪点(°F)
158.0 °F - closed cup
闪点(°C)
70 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
其他客户在看
W.H. Pirkle and J. Finn et al.
Asymmetric Synthesis, 1 (1983)
R.W. Souter
Chromatographic Separations of Stereoisomers null
Easy-on, easy-off?resolution of chiral 1-phenylethylamine catalyzed by Candida antarctica lipase B.
Torres-Gavilan, A., et al.
Tetrahedron Asymmetry, 18.22, 2621-2624 (2007)
Karim Engelmark Cassimjee et al.
Organic & biomolecular chemistry, 10(28), 5466-5470 (2012-06-13)
For biocatalytic production of pharmaceutically important chiral amines the ω-transaminase enzymes have proven useful. Engineering of these enzymes has to some extent been accomplished by rational design, but mostly by directed evolution. By use of a homology model a key
Yan-Song Zheng et al.
Chemical communications (Cambridge, England), (32)(32), 3398-3400 (2007-11-21)
Chiral para-tert-butylcalix[4]arene bearing (S)-alpha-methylbenzylamine groups at lower rim only self-assembles with one of two enantiomers of 2,3-dibenzoyltartaric acid into coiled nanofibers and the coiled nanofibers only stack with the nanofibers having the same handedness to construct bigger ribbon-like fibers bearing
Chromatograms
HPLC Analysis of α-Methylbenzylamine Enantiomers (DANSYL Derivatives) on Astec® CYCLOBOND I 2000 DMP
application for HPLCapplication for HPLC我们的科学家团队拥有各种研究领域经验,包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
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