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726621

Sigma-Aldrich

(R)-(+)-α-甲基苄胺

produced by BASF, ChiPros®, ≥99.0%

别名:

(R)-(+)-1-苯乙胺

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About This Item

线性分子式:
C6H5CH(CH3)NH2
CAS号:
3886-69-9
分子量:
121.18
Beilstein:
2410916
EC 号:
223-423-4
MDL编号:
MFCD00064405
UNSPSC代码:
12352116
PubChem化学物质编号:
329764252
NACRES:
NA.22
价格与库存信息目前不能提供

等级

produced by BASF

蒸汽压

0.5 mmHg ( 20 °C)

方案

≥99.0% (GC)
≥99.0%

表单

liquid

光学纯度

enantiomeric excess: ≥98.0%

折射率

n20/D 1.526 (lit.)

沸点

187-189 °C (lit.)

密度

0.952 g/mL at 20 °C (lit.)

官能团

amine
phenyl

SMILES字符串

C[C@@H](N)c1ccccc1

InChI

1S/C8H11N/c1-7(9)8-5-3-2-4-6-8/h2-7H,9H2,1H3/t7-/m1/s1

InChI key

RQEUFEKYXDPUSK-SSDOTTSWSA-N

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相关类别

一般描述

(R)-(+)-α-Methylbenzylamine is a chiral amine.[1]

应用

(R)-(+)-α-Methylbenzylamine may be used as a substrate to synthesize:
  • (S)-α-amino phosphonates[2]
  • N-{(S)-[cyclohexan-(S)-2-ol]}-(R)-α-methylbenzyl amine and N-{(R)-[cyclohexan-(R)-2-ol]}-(R)-α-methylbenzyl amine[3]
  • R-α-aminonitriles[2]

法律信息

ChiPros is a registered trademark of BASF SE

象形图

CorrosionExclamation mark
GHS05,GHS07

警示用语：

Danger

危险声明

H302 + H312,H314

危险分类

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

储存分类代码

8A - Combustible corrosive hazardous materials

WGK

WGK 1

闪点(°F)

158.0 °F - closed cup

闪点(°C)

70 °C - closed cup

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCBQ9373V
BCBM5250V
BCBG4718V
BCBC4052
BCBC4052V

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DL-1-Phenylethylamine for synthesis

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8.21256

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L-(+)-酒石酸 ACS reagent, ≥99.5%

Sigma-Aldrich

251380

L-(+)-酒石酸

氯仿 contains 100-200 ppm amylenes as stabilizer, ≥99.5%

Sigma-Aldrich

C2432

氯仿

Lithium perchlorate/diethylether catalyzed aminophosphonation of aldehydes.
Heydari A, et al.
Tetrahedron Letters, 39(37), 6729-6732 (1998)
New enantiomerically pure aminoalcohols from (R)-a-methylbenzylamine and cyclohexene oxide.
Barbaro P, et al.
Tetrahedron Asymmetry, 7(3), 843-850 (1996)
ChiPros Chiral Amines
Aldrich Chemfiles, 11(1) null
Karim Engelmark Cassimjee et al.
Organic & biomolecular chemistry, 10(28), 5466-5470 (2012-06-13)
For biocatalytic production of pharmaceutically important chiral amines the ω-transaminase enzymes have proven useful. Engineering of these enzymes has to some extent been accomplished by rational design, but mostly by directed evolution. By use of a homology model a key
Bartosz Lewandowski et al.
Chemical communications (Cambridge, England), (47)(47), 6399-6401 (2008-12-03)
Simple chiral aza-crown ethers based on sucrose display high enantioselectivity in complexation of phenylethylammonium chlorides.
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商品

ChiPros Chiral Amines

Chiral amines play an important role in stereoselective organic synthesis. They are used directly as resolving agents, building blocks, or chiral auxiliaries.

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