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Merck
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文件

T53805

Sigma-Aldrich

三氯乙腈

98%

别名:

Trichlorocyanomethane, Tritox

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About This Item

线性分子式:
Cl3CCN
CAS号:
545-06-2
分子量:
144.39
Beilstein:
605572
EC號碼:
208-885-7
MDL號碼:
MFCD00001842
分類程式碼代碼:
12352117
PubChem物質ID:
24900271
NACRES:
NA.22

蒸汽壓力

58 mmHg ( 20 °C)

品質等級

200

化驗

98%

折射率

n20/D 1.441 (lit.)

bp

83-84 °C (lit.)

密度

1.44 g/mL at 25 °C (lit.)

SMILES 字串

ClC(Cl)(Cl)C#N

InChI

1S/C2Cl3N/c3-2(4,5)1-6

InChI 密鑰

DRUIESSIVFYOMK-UHFFFAOYSA-N

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應用

用于通过 DBU 催化的烯丙醇加成反应合成三氯乙酰亚胺酯，以及用于 MOM 催化型氮杂-Claisen 重排反应的后续研究。还可用于由二醇制备双三氯乙酰亚胺酯，再通过酸催化的环化反应生成二氢噁嗪。

象形圖

Skull and crossbonesEnvironment
GHS06,GHS09

訊號詞

Danger

危險分類

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 2

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類（WGK）

WGK 3

閃點（°F）

165.2 °F

閃點（°C）

74 °C

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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4-甲氧基苄基-2,2,2-三氯亚氨逐乙酸酯

Sigma-Aldrich

679585

4-甲氧基苄基-2,2,2-三氯亚氨逐乙酸酯

Christophe Rondot et al.
Organic letters, 9(2), 247-250 (2007-01-16)
An efficient synthesis of chiral dihydrooxazines (2) from 1-aryl-2-amino-propane-1,3-diols (1) via the corresponding bistrichloroacetimidate intermediates has been developed. In this transformation, one trichloroacetimidate acts as a leaving group and the other acts as a nucleophile. The cyclization proceeds through an
Tetrahedron, 63, 2123-2123 (2007)
E L Lin et al.
Cancer letters, 62(1), 1-9 (1992-02-14)
Male Fisher 344 rats were administered 1- or 2-[14C]trichloroacetonitrile (TCAN) by oral gavage. DNA was isolated from the liver, kidneys and stomach and several protein fractions (globin, albumin and globulins) were isolated from blood. TCAN binds to both the DNA
M K Smith et al.
Teratology, 38(2), 113-120 (1988-08-01)
Trichloroacetonitrile (TCAN) is among a number of contaminants found in drinking water produced by reactions of chlorine with background organic material. Long-Evans rats were intubated with TCAN (0, 1, 7.5, 15, 35, 55 mg/kg) in a tricaprylin vehicle on gestation
Trichloroacetonitrile.
IARC monographs on the evaluation of carcinogenic risks to humans, 71 Pt 3, 1533-1537 (1999-09-07)
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