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Merck
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文件

531979

Sigma-Aldrich

(S,S)-N,N′-双(3,5-二-叔丁基亚水杨基)-1,2-环己二胺氯化铝

别名:

(S,S)-N,N′-双(3,5-二-叔丁基亚水杨基)-1,2-环己二胺氯化铝(III)

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About This Item

经验公式（希尔记法）:
C36H52AlClN2O2
CAS号:
307926-51-8
分子量:
607.24
MDL號碼:
MFCD02684548
分類程式碼代碼:
12352101
PubChem物質ID:
24877851
NACRES:
NA.22

mp

>350 °C (lit.)

SMILES 字串

CC(C)(C)c1cc2\C=N\[C@H]3CCCC[C@@H]3\N=C\c4cc(cc(c4O[Al](Cl)Oc2c(c1)C(C)(C)C)C(C)(C)C)C(C)(C)C

InChI

1S/C36H54N2O2.Al.ClH/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;;/h17-22,29-30,39-40H,13-16H2,1-12H3;;1H/q;+3;/p-3/b37-21+,38-22+;;/t29-,30-;;/m0../s1

InChI 密鑰

KGVBCKDZFMLRMA-RUIQGICGSA-K

相关类别

應用

(S,S)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride can be used as a chiral catalyst:
  • In the preparation of substituted hydroxyalkyl aminooxazole derivatives by reacting isocyanides with aldehydes.
  • In the cyanation of α,β-unsaturated imides to yield saturated imides.

法律資訊

经 Shasun Chemicals and Drugs Limited 授权销售。

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H302 + H312 + H332

危險分類

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves

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Sigma-Aldrich

416932

(1R,2R)-(+)-1,2-二氨基环己烷 L-酒石酸酯

Glenn M Sammis et al.
Journal of the American Chemical Society, 126(32), 9928-9929 (2004-08-12)
Cooperative heterobimetallic catalysis was used as a design principle to achieve a highly reactive system for the enantioselective conjugate addition of cyanide to alpha,beta-unsaturated imides. A dual-catalyst pathway involving chiral (salen)Al complex 1b and chiral (pybox)Er complex 4b provides measurable
Highly enantioselective, catalytic conjugate addition of cyanide to alpha, beta-unsaturated imides
Sammis GM and Jacobsen EN
Journal of the American Chemical Society, 125(15), 4442-4443 (2003)
Shi-Xin Wang et al.
Organic letters, 9(18), 3615-3618 (2007-08-10)
In the presence of a catalytic amount of (salen)Al(III)Cl complex (4e), reaction between alpha-isocyanoacetamides (1) and aldehydes (2) afforded the corresponding 5-aminooxazoles (3) in good yields and enantioselectivity.

商品

Salen Ligands

The first reports of salen used as ligands with manganese for asymmetric epoxidation reactions.

Salen Ligands

The first reports of salen used as ligands with manganese for asymmetric epoxidation reactions.

Salen Ligands

The first reports of salen used as ligands with manganese for asymmetric epoxidation reactions.

Salen Ligands

The first reports of salen used as ligands with manganese for asymmetric epoxidation reactions.

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