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Sigma-Aldrich

六氟磷酸四乙氰铜

97%

别名:

四氟化亚铜（乙腈）六氟磷酸盐, 铜（I）四（乙腈）六氟磷酸盐

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About This Item

线性分子式:
[(CH3CN)4Cu]PF6
CAS号:
64443-05-6
分子量:
372.72
MDL编号:
MFCD00064810
UNSPSC代码:
12161600
PubChem化学物质编号:
24861387
NACRES:
NA.22
价格与库存信息目前不能提供

方案

97%

表单

solid

反应适用性

core: copper
reagent type: catalyst

mp

160 °C (dec.) (lit.)

SMILES字符串

[Cu+].CC#N.CC#N.CC#N.CC#N.F[P-](F)(F)(F)(F)F

InChI

1S/4C2H3N.Cu.F6P/c4*1-2-3;;1-7(2,3,4,5)6/h4*1H3;;/q;;;;+1;-1

InChI key

GNQXUMGHBSAQBV-UHFFFAOYSA-N

相关类别

应用

四（乙腈）铜（I）六氟磷酸盐可分别通过芳醛、双甲酮和尿唑或邻苯二甲酰肼的反应，用作合成三唑并[1,2-a]吲唑-1,3,8-三酮和2H-吲唑并[2,1-b]酞嗪-三酮衍生物的催化剂。[1]
它也可以用作铜前体：
  • 通过阳离子交换过程，用于形成铜2S/CdS纳米棒结。[2]
  • 合成单金属铜大环双喹唑啉配体[Cu（Mabiq）]。[3]
  • 制备亚铜络合物[Cu（2-iQBO）（POP）] PF6]；其中2-iQBO = 2-（1′-异喹啉基）苯并恶唑，POP = 双[2-（二苯基膦基）苯基]醚，其可形成发光假多晶型物。[4]
  • 用于[Cu（NHC）2] PF6复合物[（NHC = N-杂环卡宾]的合成，其可进一步用于羰基化合物的氢化硅烷化。[5]

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
0000315505
0000315505
0000242952
MKCT6513
MKCR6665

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Structural Characterization and Photochemical Properties of Mono-and Bimetallic Cu-Mabiq Complexes.
Stark HS, et al.
Inorganic Chemistry, 28(9), 095705-095705 (2018)
Synthesis and characterization of [Cu (NHC)2] X complexes: Catalytic and mechanistic studies of hydrosilylation reactions.
Diez-Gonzalez S, et al.
Chemistry?A European Journal , 14(1), 158-168 (2008)
Two luminescent pseudo-polymorphic cuprous complexes with different optical properties: Synthesis, characterization and TD-DFT calculations.
Tao XD, et al.
Polyhedron, 144(9), 36-43 (2018)
Tetrakis (acetonitrile) copper (I) Hexafluorophosphate as an Efficient Catalyst for the Synthesis of Triazolo [1, 2-a] indazole-1, 3, 8-trione and 2Hindazolo [2, 1-b] phthalazine-trione Derivatives.
Azarifar D, et al.
Letters in Organic Chemistry, 9(2), 128-132 (2012)
Biswajit Kundu et al.
Nanotechnology, 28(9), 095705-095705 (2017-01-31)
Through scanning tunneling spectroscopy, we envisage imaging a heterostructure, namely a junction formed in a single nanorod. While the differential conductance spectrum provides location of conduction and valence band edges, dI/dV images record energy levels of materials. Such dI/dV images
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      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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