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Merck
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文件

288055

Sigma-Aldrich

三羰基环戊二烯锰(I)

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About This Item

线性分子式:
C5H5Mn(CO)3
CAS号:
12079-65-1
分子量:
204.06
EC號碼:
235-142-4
MDL號碼:
MFCD00001440
分類程式碼代碼:
12352103
PubChem物質ID:
24857312
NACRES:
NA.23

品質等級

100

形狀

powder or crystals

成份

Mn, 26.0-27.9% EDTA titration

反應適用性

core: manganese
reagent type: catalyst

mp

72-76 °C (lit.)

SMILES 字串

[Mn].[C-]#[O+].[C-]#[O+].[C-]#[O+].[CH]1[CH][CH][CH][CH]1

InChI

1S/C5H5.3CO.Mn/c1-2-4-5-3-1;3*1-2;/h1-5H;;;;

InChI 密鑰

CZPHEHHRMHXAIK-UHFFFAOYSA-N

相关类别

象形圖

Skull and crossbones
GHS06

訊號詞

Danger

危險聲明

H300

防範說明

P264 - P301 + P310

危險分類

Acute Tox. 2 Oral

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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羰基钴 moistened with hexane (hexane 1-10%), ≥90% (Co)

Sigma-Aldrich

60811

羰基钴

苯三羰基铬 98%

Sigma-Aldrich

119318

苯三羰基铬

Magdaléna Hromadová et al.
Langmuir : the ACS journal of surfaces and colloids, 22(1), 506-511 (2005-12-28)
A first example of the solid-phase immunoassay of a high-weight antigen bovine serum albumin (BSA) using an (eta(5)-cyclopentadienyl)tricarbonylmanganese (cymantrene) redox probe is presented. The electrochemical detection is based on the impedance measurements of a one-electron reversible reduction of the organometallic
R J Clay et al.
Toxicology and applied pharmacology, 98(3), 434-443 (1989-05-01)
The acute pneumotoxic effects of cyclopentadienyl manganese tricarbonyl (CMT) and methylcyclopentadienyl manganese tricarbonyl (MMT) were compared to delineate the role of the methyl side chain in the toxicity of these organomanganese compounds and to further our understanding of the mechanisms
K T Blanchard et al.
Toxicology letters, 70(2), 253-259 (1994-02-01)
The effect of m-xylene on the rat nasal cytochrome P450 (P450) mixed function oxidase system was analyzed in vitro utilizing microsomes isolated 2, 12, and 24 h following intraperitoneal administration of this solvent in vivo. For comparative purposes, pulmonary and
I Rémy et al.
Journal of pharmaceutical and biomedical analysis, 9(10-12), 965-967 (1991-01-01)
Biotin labelled with a cymantrene moiety (cyclopentadienyl manganese tricarbonyl complex) is described for the first time. Because this metallo-biotin retains full recognition for the specific glycoprotein avidin (or streptavidin), the labelled streptavidin-biotin system is proposed for use in a solid-phase
M Salmain et al.
Journal of immunological methods, 148(1-2), 65-75 (1992-04-08)
A new non-radioisotopic immunoassay procedure, which we have termed carbonylmetalloimmunoassay (CMIA), is described. The tracers used in this approach are organometallic carbonyl complexes that can be detected at femtomole levels (300-700 fmol) by Fourier transform infrared (FT-IR) spectroscopy. The validity
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