M9653

Methoxyacetylchlorid

97%

• Synonym(e): Methoxyacetylchlorid
• Lineare Formel: CH₃OCH₂COCl
• CAS-Nummer: 38870-89-2
• Molekulargewicht: 108.52
• Beilstein: 1740244
• EG-Nummer: 254-169-2
• MDL-Nummer: MFCD00000728
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24897347
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 100
• Assay: 97%
• Form: liquid
• Brechungsindex: n20/D 1.419 (lit.)
• bp: 112-113 °C (lit.)
• Dichte: 1.187 g/mL at 25 °C (lit.)
• Lagertemp.: 2-8°C
• SMILES String: COCC(Cl)=O
• InChI: 1S/C3H5ClO2/c1-6-2-3(4)5/h2H2,1H3
• InChIKey: JJKWHOSQTYYFAE-UHFFFAOYSA-N

Beschreibung

Anwendung

Methoxyacetyl chloride can be used for methoxyacetylation of:

• Bilocularin A to synthesize 8-Methoxyacetoxybilocularin A.
• Substituted and unsubstituted benzamides to synthesize N-(2-methoxyacetyl)-benzamides.

It can also be used for the synthesis of β-lactams by reacting with imines. and in the post-synthetic modification of the metal-organic framework (MOF), MIL-101, to synthesize a catalyst for cycloaddition reaction of CO₂ with propylene oxide.

Sicherheitshinweise

• Piktogramme: GHS02,GHS06,GHS05
• Signalwort: Danger
• H-Sätze: H226,H314,H331,H335
• P-Sätze: P210 - P233 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Gefahreneinstufungen: Acute Tox. 3 Inhalation - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 3
• Flammpunkt (°F): 82.4 °F
• Flammpunkt (°C): 28 °C
• Persönliche Schutzausrüstung: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter