804215

[Ir{dFCF₃ppy}₂(bpy)]PF₆

• Synonym(e): [Ir[dF(CF3)2ppy]2(bpy)]PF6
• Empirische Formel (Hill-System): C₃₄H₁₈F₁₆IrN₄P
• CAS-Nummer: 1092775-62-6
• Molekulargewicht: 1009.70
• MDL-Nummer: MFCD28987331
• UNSPSC-Code: 12161600
• PubChem Substanz-ID: 329768852
• NACRES: NA.22

Eigenschaften

• Form: powder
• Qualitätsniveau: 100
• Eignung der Reaktion: core: iridium; reagent type: catalyst; reaction type: Photocatalysis
• Photokatalysatoraktivierung: 450 nm
• SMILES String: FP(F)(F)(F)F.FC1=CC(F)=C(C2=[N]3C=C(C(F)(F)F)C=C2)C([Ir+]345([N]6=C(C7=CC=CC=[N]75)C=CC=C6)[N]8=C(C9=C(F)C=C(F)C=C94)C=CC(C(F)(F)F)=C8)=C1.[F-]
• InChI: 1S/2C12H5F5N.C10H8N2.F5P.FH.Ir/c2*13-8-2-3-9(10(14)5-8)11-4-1-7(6-18-11)12(15,16)17;1-3-7-11-9(5-1)10-6-2-4-8-12-10;1-6(2,3,4)5;;/h2*1-2,4-6H;1-8H;;1H;/q;;;;;+1/p-1
• InChIKey: DZIQZTFRUCLPRL-UHFFFAOYSA-M

Beschreibung

Anwendung

When used in tandem with a nickel catalyst, the above photoredox catalyst effects the cross-coupling of C-sp³ hybridized trifluoroborates with aryl bromides under exceptionally mild conditions.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable