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Merck
모든 사진(5)

주요 문서

311448

Sigma-Aldrich

Sodium periodate

ACS reagent, ≥99.8%

동의어(들):

Sodium (meta)periodate

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크기 선택

5 G
₩79,982
100 G
₩342,867
500 G
₩1,091,125

₩79,982


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벌크 견적 요청

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보기 변경
5 G
₩79,982
100 G
₩342,867
500 G
₩1,091,125

About This Item

Linear Formula:
NaIO4
CAS Number:
Molecular Weight:
213.89
EC Number:
MDL number:
UNSPSC 코드:
12352302
PubChem Substance ID:
NACRES:
NA.21
분석:
≥99.8%
99.8-100.3% dry basis (ACS specification)
Grade:
ACS reagent
양식:
crystalline powder

₩79,982


재고 있음세부사항


벌크 견적 요청

Grade

ACS reagent

Quality Level

분석

≥99.8%
99.8-100.3% dry basis (ACS specification)

양식

crystalline powder

반응 적합성

reagent type: oxidant

불순물

≤0.02% other halogens (as Cl)

pH

3.5-5.5 (25 °C, 107 g/L)

mp

300 °C (dec.) (lit.)

양이온 미량물

Mn: ≤3 ppm

저장 온도

room temp

SMILES string

[Na+].[O-]I(=O)(=O)=O

InChI

1S/HIO4.Na/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1

InChI key

JQWHASGSAFIOCM-UHFFFAOYSA-M

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일반 설명

Sodium periodate is an inorganic salt commonly used as an oxidizing agent for various organic substrates and a co-oxidant in a few other oxidation reactions. The oxidation of sodium periodate takes place in a water medium, but an organic co-solvent is used for organic substrates that are insoluble in water.

애플리케이션

Sodium periodate can be used as an oxidizing agent:
  • In the selective oxidation of sulfides to sulfoxides.
  • For the oxidative cleavage of a variety of 1,2-diols to generate aldehydes or ketones.
  • In the oxidation of diaryl, dialkyl, and aryl alkyl selenides to the respective selenoxides.
  • In the selective alkene epoxidation and alkane hydroxylation reactions.
  • In the selective oxidation of activated cellulose to obtain dialdehyde cellulose (DAC) by cleavage of the bond between C2 – C3 in the glucose unit.
  • It can also be used as an iodinating agent for the iodination of arenes and halo compounds.

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Ox. Sol. 1 - Skin Corr. 1C - STOT RE 1

표적 기관

Thyroid

Storage Class Code

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable


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질문

1–3 / 3 질문  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 답변
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 답변
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  3. Is NaIO4 stable in water? Can it be stored as solution, or should it be prepared from powder each time before experiment?

    1 답변
    1. The solution stability of this material has not been determined. A conservative approach would be to prepare fresh with each use.

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