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Merck
모든 사진(2)

문서

905100

Sigma-Aldrich

Ir(p-tBu-ppy)3

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About This Item

실험식(Hill 표기법):
C45H48IrN3
CAS Number:
Molecular Weight:
823.10
UNSPSC 코드:
12352101
NACRES:
NA.22

형태

powder

반응 적합성

reaction type: Photocatalysis
reagent type: catalyst

관련 제품

제품 번호
설명
가격

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable


시험 성적서(COA)

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문서 라이브러리 방문

Xiao-Jing Wei et al.
ACS catalysis, 7(10), 7136-7140 (2017-11-08)
The development of synthetic methodologies which provide access to both stereoisomers of α,β-disubstituted olefins is a challenging undertaking. Herein, we describe the development of an operationally simple and stereoselective synthesis of difluoromethylated styrenes via a visible-light photocatalytic decarboxylation strategy using
Eric D Nacsa et al.
Journal of the American Chemical Society, 140(9), 3322-3330 (2018-02-06)
Nature routinely engages alcohols as leaving groups, as DNA biosynthesis relies on the removal of water from ribonucleoside diphosphates by a radical-mediated "spin-center shift" (SCS) mechanism. Alcohols, however, remain underused as alkylating agents in synthetic chemistry due to their low
Amandeep Arora et al.
Organic letters, 18(16), 3996-3999 (2016-08-06)
The 2-azolyl radical, generated from 2-bromoazoles via photocatalysis, is a powerful intermediate for the intermolecular arylation of unmodified (hetero)arenes. The reaction is characterized by mild conditions, operational simplicity, tolerance toward functional and sterically demanding groups, broad scope, and anti-Minisci selectivity.
Facile synthesis and complete characterization of homoleptic and heteroleptic cyclometalated Iridium(III) complexes for photocatalysis
Singh A, et al.
Journal of Organometallic Chemistry, 776, 51-59 (2015)

관련 콘텐츠

Organofluorine chemistry is an essential part of drug discovery programs as well as agrochemical programs and even plays a major role in materials chemistry. Despite the undeniable importance of fluorinated organic molecules, our ability to synthesize these substrates is lacking - though arguably it is better than that of Nature. Consequently, methods that allow facile access to fluorinated molecules are important especially when they provide unique access to fluorinated chemical space.

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