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Merck
모든 사진(2)

주요 문서

747793

Sigma-Aldrich

(Ir[dF(CF3)ppy]2(dtbpy))PF6

동의어(들):

[Ir{dF(CF3)ppy}2(dtbpy)]PF6, [4,4′-Bis(1,1-dimethylethyl)-2,2′-bipyridine-N1,N1′]bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]Iridium(III) hexafluorophosphate

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크기 선택

100 MG
₩247,457
1 G
₩1,188,971

₩247,457


예상 입고일2025년 2월 03일세부사항


벌크 견적 요청

크기 선택

보기 변경
100 MG
₩247,457
1 G
₩1,188,971

About This Item

실험식(Hill 표기법):
C42H34F16IrN4P
CAS Number:
Molecular Weight:
1121.91
MDL number:
UNSPSC 코드:
12161600
NACRES:
NA.22

₩247,457


예상 입고일2025년 2월 03일세부사항


벌크 견적 요청

양식

solid

Quality Level

반응 적합성

core: iridium
reagent type: catalyst
reaction type: Photocatalysis

mp

>300 °C

광촉매 활성화

450 nm

SMILES string

F[P](F)(F)(F)(F)F.CC(C)(C)C1=CC=[N@H]2C(=C1)C3=CC(=CC=[N@@H]3[Ir]2456c7cc(F)cc(F)c7C8=CC=C(C=[N]48)C(F)(F)F)C(C)(C)C.Fc9cc(F)c(C%10=[N]5C=C(C=C%10)C(F)(F)F)c6c9

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애플리케이션

(Ir[dF(CF3)ppy]2(dtbpy))PF6 is a cyclometalated iridium(III) complex that can be used in visible-light mediated photocatalytic organic transformations.[1][2][3][4][5]It has been used to achieve late-stage incorporation of alkyl groups to a variety of biologically active heterocycles.[3]

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable


가장 최신 버전 중 하나를 선택하세요:

시험 성적서(COA)

Lot/Batch Number

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문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

A photochemical strategy for lignin degradation at room temperature.
Nguyen J D, et al.
Journal of the American Chemical Society, 136(4), 1218-1221 (2014)
Advances in Photocatalysis: A Microreview of Visible Light Mediated Ruthenium and Iridium Catalyzed Organic Transformations.
Teegardin K, et al.
Organic Process Research & Development, 20(7), 1156-1163 (2016)
Late?Stage Functionalization of Biologically Active Heterocycles Through Photoredox Catalysis.
DiRocco D A et al.
Angewandte Chemie (International Edition in English), 53(19), 4802-4806 (2014)
Formal Total Synthesis of l-Ossamine via Decarboxylative Functionalization Using Visible-Light-Mediated Photoredox Catalysis in a Flow System.
Inuki S, et al.
The Journal of Organic Chemistry, 82(2), 1248-1253 (2017)
Radical Carbon?Carbon Bond Formations Enabled by Visible Light Active Photocatalysts.
Wallentin C J, et al.
Chimia, 66(6), 394-398 (2012)

관련 콘텐츠

Research in the Stephenson lab focuses upon the development of new chemical methods which enable the activation of chemical bonds under mild reaction conditions.

Explore reliable, premium grade catalysis materials for your pharma or industrial project. Specialty chemicals and formulations are available in bulk quantities and volumes from a few grams to multi-metric tons with complete documentation to simplify your leap from development to commercialization.

질문

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 답변
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 답변
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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