688096

Tris[2-phenylpyridinato-C²,N]iridium(III)

97%

• 동의어(들): Ir(ppy)₃, Iridium, tris[2-(2-pyridinyl-κN)phenyl-κC]
• 실험식(Hill 표기법): C₃₃H₂₄IrN₃
• CAS Number: 94928-86-6
• Molecular Weight: 654.78
• MDL number: MFCD12022527
• UNSPSC 코드: 12352103
• PubChem Substance ID: 329760833
• NACRES: NA.23

속성

• 설명: fac-Tris[2-phenylpyridinato-C₂,N]iridium(III)
• Quality Level: 100
• 분석: 97%
• 양식: powder
• 반응 적합성: core: iridium; reaction type: Photocatalysis; reagent type: catalyst
• 광촉매 활성화: 425 nm
• 형광: λ_ex 340 nm; λ_em 512 nm in chloroform
• 오비탈 에너지: HOMO 5.6 eV ; LUMO 3 eV
• OLED 기기 성능: ITO/HMPD/TAZ:Ir(ppy)₃ (7%)/Alq₃/Al:Li;
  • Color: green
  • Max. Luminance: 4000 Cd/m²
  • Max. EQE: 15 %
  ; ITO/NPD/CBP:Ir(ppy)₃ (6%)/Alq₃/Mg:Ag;
  • Color: green
  • Max. Luminance: 100000 Cd/m²
  • Max. EQE: 8 %
  • Turn-On Voltage: 4.3 V
  ; ITO/NPD/TCTA/BCPO:Ir(ppy)₃ (7-8%)/BCP/Alq₃/LiF/Al;
  • Color: green
  • Max. Luminance: 207839 Cd/m²
  • Max. EQE: 21.6 %
  • Turn-On Voltage: 2.1 V
  ; ITO/TCTA/Ir(ppy)₃/Bphen/LiF/Al;
  • Color: green
  • Max. Luminance: 300000 Cd/m²
  • Max. EQE: 19 %
  • Turn-On Voltage: 2.6 V
• SMILES string: c1ccc(nc1)-c2ccccc2[Ir](c3ccccc3-c4ccccn4)c5ccccc5-c6ccccn6
• InChI: 1S/3C11H8N.Ir/c3*1-2-6-10(7-3-1)11-8-4-5-9-12-11;/h3*1-6,8-9H;
• InChI key: QKBWDYLFYVXTGE-UHFFFAOYSA-N

설명

일반 설명

Tris-(2-phenylpyridine) iridium [Ir(ppy)₃] is a heavy metal complex. [Ir(ppy)₃] is the most frequently used precursor molecule for the synthesis of electro-phosphorescent materials, which are then used in organic light emitting diodes (OLEDs). It provides green-color emission and high phosphorescence quantum yield close to unity.[1][2]

애플리케이션

Learn More at the Professor and Product Portal of Professor Corey Stephenson.

Put to elegant use by Stephenson for the reduction of alkyl, alkenyl and aryl iodides in the presence of visible light. Intramolecular reductive cyclizations were also achieved with this catalyst.

Engaging unactivated alkyl, alkenyl and aryl iodides in visible-light-mediated free radical reactions

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

안전성 정보

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: dust mask type N95 (US), Eyeshields, Gloves