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Merck
모든 사진(1)

주요 문서

379433

Sigma-Aldrich

2,6-Bis(2-benzimidazolyl)pyridine

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1 G
₩87,290

₩87,290


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1 G
₩87,290

About This Item

실험식(Hill 표기법):
C19H13N5
CAS Number:
Molecular Weight:
311.34
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22

₩87,290


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Quality Level

mp

>300 °C (lit.)

SMILES string

c1cc(nc(c1)-c2nc3ccccc3[nH]2)-c4nc5ccccc5[nH]4

InChI

1S/C19H13N5/c1-2-7-13-12(6-1)21-18(22-13)16-10-5-11-17(20-16)19-23-14-8-3-4-9-15(14)24-19/h1-11H,(H,21,22)(H,23,24)

InChI key

JBKICBDXAZNSKA-UHFFFAOYSA-N

일반 설명

2,6-Bis(2-benzimidazolyl)pyridine acts as tridentate nitrogen donor ligand and reacts with UO2Cl2·3THF to form complexes.[1] It is reported as an efficient anion receptor providing chemical shift and optical modification based signals for the detection of acetate ions.[2] 2,6-bis(2-benzimidazolyl)pyridine is a V-shaped ligand and its picrate Mn(II) complex has been prepared.[3] 2,6-Bis(2-benzimidazolyl)pyridine is also reported as an optical sensor useful for the aniline recognition.[4]

애플리케이션

2,6-Bis(2-benzimidazolyl)pyridine may be employed as a chemosensor for the detection of fluoride ions.[5] It may be used as a sensor for the detection of toxic metabolites of benzene such as phenol, hydroquinone, resorcinol, catechol and p-benzoquinone.[6]

픽토그램

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신호어

Warning

유해 및 위험 성명서

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

표적 기관

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

dust mask type N95 (US), Eyeshields, Gloves


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문서 라이브러리 방문

Liming Zhang et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 74(5), 1060-1063 (2009-10-17)
In this paper, an optical sensor, 2,6-bis(2-benzimidazolyl)pyridine, is reported to be highly selective towards aniline. A unique spectral response of 2,6-bis(2-benzimidazolyl)pyridine towards aniline is found, and a linear relationship between the sensor's emission intensity and the aniline's concentration is observed
Utilization of 2, 6-bis (2-benzimidazolyl) pyridine to detect toxic benzene metabolites.
Chetia B and Iyer PK.
Tetrahedron Letters, 48(1), 47-50 (2007)
Roy Copping et al.
Inorganic chemistry, 53(5), 2506-2515 (2014-02-18)
The reaction of UO2Cl2·3THF with the tridentate nitrogen donor ligand 2,6-bis(2-benzimidazolyl)pyridine (H2BBP) in pyridine leads to the formation of three different complexes: [(UO2)(H2BBP)Cl2] (1), [(UO)2(HBBP)(Py)Cl] (2), and [(UO2)(BBP)(Py)2] (3) after successive deprotonation of H2BBP with a strong base. Crystallographic determination
2, 6-Bis (2-benzimidazolyl) pyridine as a chemosensor for fluoride ions.
Chetia B and Iyer PK.
Tetrahedron Letters, 49(1), 94-97 (2008)
Bolin Chetia et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 81(1), 313-316 (2011-07-12)
2,6-Bis(2-benzimidazolyl)pyridine, bbp, a simple tridentate ligand, is employed as a receptor for the recognition of anions. The binding of anionic guest species with bbp can be studied in short duration using UV/vis spectroscopy, fluorescence spectroscopy and (1)H NMR techniques at

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