402990

一塩化ヨウ素

ACS reagent, 1.10±0.1 I/Cl ratio basis

• 別名: 塩化ヨウ素
• 化学式: ICl
• CAS番号: 7790-99-0
• 分子量: 162.36
• EC Number: 232-236-7
• MDL番号: MFCD00011354
• UNSPSCコード: 12352300
• PubChem Substance ID: 329755974
• NACRES: NB.24

特性

• グレード: ACS reagent
• 形状: solid or liquid
• 不純物: ≤0.005% insolubles
• bp: 97.4 °C (lit.)
• 溶解性: acetic acid: soluble(lit.); acetone: soluble(lit.); alcohol: soluble(lit.); carbon disulfide: soluble(lit.)
• 密度: 3.24 g/mL at 25 °C (lit.)
• 保管温度: 2-8°C
• SMILES記法: ClI
• InChI: 1S/ClI/c1-2
• InChI Key: QZRGKCOWNLSUDK-UHFFFAOYSA-N

詳細

詳細

Iodine monochloride is an interhalogen compound. It forms various complexes with ethyl, isopropyl and t-butylbenzenes. Equilibrium constants for the formation of these complexes have been evaluated. It affords electrically conducting solution on dissolution in polar solvents. Its reaction with thymidine, 3-mono- and 3,3′,5′-trialkylsubstitued thymidine showed that it helps in deglycosylation, anomerization and isomerization of thymidine.

アプリケーション

Iodine monochloride (ICl) may be employed for the halogenation of methoxy and dimethoxybenzenes. It may be used for the synthesis of flavones.

Iodine monochloride may be used in the synthesis of the following:

• 2-(4-haloisoquinolin-1-yl)ethanol derivatives
• 5-iodosalicylaldehydes
• 5-aryl-6-iodo-8-phenylpyrazolo[1,5-c]-1,2,4-triazolo[4,3-a]pyrimidines
• (±)-1-cyclohexyl-4-iodo-3-methoxybutan-1-ol
• (±)-4-Iodo-3-methoxy-1-phenylbutan-1-ol

安全性情報

• ピクトグラム: GHS05,GHS07
• シグナルワード: Danger
• 危険有害性情報: H314,H335
• 注意書き: P261 - P271 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• 危険有害性の分類: Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
• ターゲットの組織: Respiratory system
• 保管分類コード: 8B - Non-combustible corrosive hazardous materials
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable