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Merck

1.05426

Supelco

Ammonia solution

32%, EMPLURA®

別名:

アンモニア水

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About This Item

化学式:
NH4OH
CAS番号:
分子量:
35.05
Beilstein:
3587154
MDL番号:
UNSPSCコード:
12352402
NACRES:
NA.21
Pricing and Inventory is not available. Please check the Merck website for more information.

製品名

水酸化アンモニウム 溶液, EMPLURA®

蒸気圧

837 hPa ( 20 °C)

品質水準

製品種目

EMPLURA®

フォーム

liquid

expl. lim.

27 %

濃度

≥30% (NH3, acidimetric)

不純物

≤0.0001% Heavy metals (as Pb)
≤0.0005% Fe (Iron)
≤0.0008% Substances reducing potassium permanganate (as O)
≤0.002% Chloride (Cl)
≤0.003% Sulphate (SO?)

強熱残分

≤0.003% (as sulphates)

APHA: ≤10

bp

37.7 °C/1013 hPa

mp

-91.5 °C

密度

0.9 g/mL at 25 °C (lit.)

保管温度

2-30°C

SMILES記法

[NH4+].[OH-]

InChI

1S/H3N.H2O/h1H3;1H2

InChI Key

VHUUQVKOLVNVRT-UHFFFAOYSA-N

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関連するカテゴリー

アプリケーション


  • Highly Efficient Recovery of Au(I) from Gold Leaching Solution Using Sodium Dimethyldithiocarbamate.: This study explores the effective recovery of gold using sodium dimethyldithiocarbamate in an ammonia-rich environment, highlighting the interaction with ammonia solution and its impact on the leaching process (Yang et al., 2024).

  • Oxidation mechanism of pyrite in a thiosulfate solution: electrochemical impedance (EIS) and in situ Raman spectroscopy.: Explores the oxidation processes of pyrite in thiosulfate solutions facilitated by ammonia, examining the electrochemical properties and kinetics involved in the oxidation mechanism (Tamayo et al., 2023).

包装

Due to quality and safety aspects Ammonia Solution will no longer be offered in glass bottles but solely in HDPE bottles.

Please note the following replacements:
1054261000 (1 L glass bottle) replaced by 1054261011 (1 L HDPE bottle)
1054262500 (2.5 L glass bottle) replaced by 1054262511 (2.5 L HDPE bottle)

More information about our ergonomic and unbreakable HDPE bottles can be found here: www.SigmaAldrich.com/hdpe-bottle

アナリシスノート

Assay (acidimetric, NH₃): ≥ 30 %
Identity: passes test
Colour: ≤ 10 Hazen
Chloride (Cl): ≤ 0.002 %
Sulphate (SO₄): ≤ 0.003 %
Heavy metals (as Pb): ≤ 0.0001 %
Fe (Iron): ≤ 0.0005 %
Substances reducing potassium permanganate (as O): ≤ 0.0008 %
Residue on ignition (as sulphates): ≤ 0.003 %

法的情報

EMPLURA is a registered trademark of Merck KGaA, Darmstadt, Germany

ピクトグラム

CorrosionExclamation markEnvironment

シグナルワード

Danger

危険有害性情報

危険有害性の分類

Aquatic Acute 1 - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

ターゲットの組織

Respiratory system

保管分類コード

8B - Non-combustible, corrosive hazardous materials

WGK

WGK 2


適用法令

試験研究用途を考慮した関連法令を主に挙げております。化学物質以外については、一部の情報のみ提供しています。 製品を安全かつ合法的に使用することは、使用者の義務です。最新情報により修正される場合があります。WEBの反映には時間を要することがあるため、適宜SDSをご参照ください。

毒物及び劇物取締法

劇物

労働安全衛生法名称等を表示すべき危険物及び有害物

名称等を表示すべき危険物及び有害物

労働安全衛生法名称等を通知すべき危険物及び有害物

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試験成績書(COA)

製品のロット番号・バッチ番号を入力して、試験成績書(COA) を検索できます。ロット番号・バッチ番号は、製品ラベルに「Lot」または「Batch」に続いて記載されています。

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プロトコル

A guide to create solvent systems used for the thin-layer chromatography assay of Novabiochem products.

関連コンテンツ

Our ergonomic 1 L HDPE bottle for acids, bases, and solvents provide an alternative to glass chemical bottles for lab safety in pouring & handling of hazardous chemicals in the laboratory.

質問

1–5/5 質問  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 回答
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      役に立ちましたか?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 回答
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      役に立ちましたか?

  3. Is the 32% NH3 concentration expressed as %w/w?

    1 回答
    1. The concentration is expressed as %w/w.

      役に立ちましたか?

  4. Is Emplura ammonia solution 32% considered technical grade or higher purity?

    1 回答
    1. This product is considered research grade.

      役に立ちましたか?

  5. you say that 28% solution of NH3 is a 56.6% NH4OH for calculating molarity. Can you explain the conversion of 28% to 56.6%? What would be the molarity of a 31% NH3 solution of ammonium hydroxide?

    1 回答
    1. It should be 57.6% NH4OH, not 56.6% NH4OH. Using 17.034 as the molecular weight for NH3 and 35.0494 as the molecular weight weight for NH4OH, the calculation would be: (28 grams NH3/100 grams of solution) X (35.0494 grams NH4OH / 17.034 grams NH3) = 57.6 grams NH4OH per 100 grams of solution, or 57.6%.

      To calculate the molarity, the density of a 31% NH3 solution is needed. For the calculation, please note that the weight percentage is for NH3, molecular weight 17.034. (31 grams of NH3 / 100 grams of solution) X (890 grams of solution / Liter of solution) X (1 mole NH3 / 17.034 grams NH3) X (1 mole NH4OH / 1 mole NH3) = 16.2 (16.197) moles NH4OH per Liter. The molarity would be 16.2 M.

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