923508

(iPrMPhos)PdCl₂

1:1 complex with CH₂Cl₂, ≥95%

• 別名: 1-Diadamantylphosphino-1′-diisopropylphosphinoferrocene palladium dichloride
• 実験式（ヒル表記法）: C₃₆H₅₂Cl₂FeP₂Pd
• 分子量: 779.92
• UNSPSCコード: 12352103
• NACRES: NA.22

特性

• 品質水準: 100
• アッセイ: ≥95%
• フォーム: powder
• 反応適合性: reagent type: catalyst; reaction type: Cross Couplings
• mp: >300 °C
• SMILES記法: ClCCl.[Cl-][Pd+2]1([Cl-])[P](C(C)C)(C(C)C)[C-]23[CH]4=[CH]5[CH]6=[CH]2[Fe+2]56789%1043[CH]=%11[CH]%10=[CH]9[C-]8([CH]%117)[P]1(C%12%13CC%14CC(CC(C%14)C%12)C%13)C%15%16CC%17CC(CC(C%17)C%15)C%16
• InChI: InChI=1S/C25H34P.C11H18P.CH2Cl2.2ClH.Fe.Pd/c1-2-4-23(3-1)26(24-11-17-5-18(12-24)7-19(6-17)13-24)25-14-20-8-21(15-25)10-22(9-20)16-25;1-9(2)12(10(3)4)11-7-5-6-8-11;2-1-3;;;;/h1-4,17-22H,5-16H2;5-10H,1-4H3;1H2;2*1H;;/q2*-1;;;;2*+2/p-2
• InChI Key: JBKBIWGRUZQRBH-UHFFFAOYSA-L

詳細

アプリケーション

(iPrMPhos)PdCl₂ is an unsymmetrical ferrocene-based Pd-catalyst. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. (iPrMPhos)PdCl₂ can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp²-Csp³ coupling. Demonstrated Csp²-Csp³ couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR₂)).

Learn more about MPhos ligands and catalysts

その他情報

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp²–Csp³ Couplings

安全性情報

• 保管分類コード: 11 - Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable