901762

Tris(dimethylamino)sulfonium bifluoride

• 別名: (Me₂N)₃S⁺[FHF]^–, Bifluoride salt SuFEx catalyst
• 実験式（ヒル表記法）: C₆H₁₉F₂N₃S
• CAS番号: 85248-37-9
• 分子量: 203.30
• UNSPSCコード: 12352101

特性

• フォーム: powder or solid
• 反応適合性: reagent type: catalyst; reaction type: Fluorinations
• 環境により配慮した代替製品の特徴: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• 環境により配慮した代替製品カテゴリ: , Aligned
• 保管温度: 2-8°C

詳細

詳細

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

アプリケーション

Bifluoride salt reported by K. Barry Sharpless and colleagues as a powerful catalyst for the sulfur(VI) fluoride exchange (SuFEx) reaction between aryl silyl ethers and aryl fluorosulfates or alkyl sulfonyl fluorides. Superior to organosuperbases DBU and BEMP, tris(dimethylamino)sulfonium bifluoride enables low catalyst loading (0.05 mol%) for preparation of polysulfates and polysulfonates with high molecular weight and narrow polydispersity. Reaction is amenable to scale up.

その他情報

Bifluoride-catalysed sulfur(VI) fluoride exchange reaction for the synthesis of polysulfates and polysulfonates

安全性情報

• 保管分類コード: 13 - Non Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable