805041

2-(trimethylsilyl)-2-cyclohexen-1-one

• 実験式（ヒル表記法）: C₉H₁₆OSi
• CAS番号: 72162-99-3
• 分子量: 168.31
• MDL番号: MFCD11502410
• UNSPSCコード: 12352100
• PubChem Substance ID: 329768917
• NACRES: NA.22

特性

• 詳細: Fp: 15.8°F
• 品質水準: 100
• フォーム: liquid
• 屈折率: n20/D 1.4524
• 密度: 0.8680 g/mL at 25 °C
• 官能基: ketone
• 保管温度: −20°C
• SMILES記法: O=C1C([Si](C)(C)C)=CCCC1
• InChI: 1S/C9H16OSi/c1-11(2,3)9-7-5-4-6-8(9)10/h7H,4-6H2,1-3H3
• InChI Key: SXGCQSJRVVKTOH-UHFFFAOYSA-N

詳細

詳細

2-(Trimethylsilyl)-2-cyclohexen-1-one is a silyl enone.

アプリケーション

The following silyl enone can be converted into a highly useful cyclohexyne precursor as reported by the Garg and DuBois groups. The resulting silyltriflate adduct can be subjected to various dienes and dipolarophiles in the presence of Cesium Fluoride.

その他情報

Cycloadditions of Cyclohexynes and Cyclopentyne

Modular synthesis of the pentacyclic core of batrachotoxin and select batrachotoxin analogue designs

安全性情報

• ピクトグラム: GHS02,GHS07
• シグナルワード: Warning
• 危険有害性情報: H228,H302
• 注意書き: P210 - P301 + P312 + P330 - P370 + P378
• 危険有害性の分類: Acute Tox. 4 Oral - Flam. Sol. 2
• 保管分類コード: 4.1B - Flammable solid hazardous materials
• WGK: WGK 3
• 引火点(°F): 15.8 °F
• 引火点(℃): -9 °C