775053

リチウムビス(トリメチルシリル)アミド 溶液

0.5 M in 2-methyltetrahydrofuran

• 別名: ヘキサメチルジシラザン リチウム塩
• 化学式: [(CH₃)₃Si]₂NLi
• CAS番号: 4039-32-1
• 分子量: 167.33
• Beilstein: 3567910
• MDL番号: MFCD00008261
• UNSPSCコード: 12352111
• PubChem Substance ID: 329767733
• NACRES: NA.22

特性

• フォーム: liquid
• 品質水準: 100
• 環境により配慮した代替製品の特徴: Safer Solvents and Auxiliaries; Use of Renewable Feedstocks; Inherently Safer Chemistry for Accident Prevention; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• 濃度: 0.5 M in 2-methyltetrahydrofuran
• 密度: 0.857 g/mL at 25 °C
• 環境により配慮した代替製品カテゴリ: Aligned,
• SMILES記法: [Li]N([Si](C)(C)C)[Si](C)(C)C
• InChI: 1S/C6H18NSi2.Li/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1
• InChI Key: YNESATAKKCNGOF-UHFFFAOYSA-N

詳細

詳細

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product, 0.5 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention. Click here for more information.

アプリケーション

ロジウム(I)触媒存在下でフェニルアセチレンの重合反応を大きく促進させます[1]。

Strong organic base in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

包装

The 25 mL Sure/Seal^™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

法的情報

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

安全性情報

• ピクトグラム: GHS02,GHS05,GHS07
• シグナルワード: Danger
• 危険有害性情報: H225,H251,H302,H314
• 注意書き: P210 - P235 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• 危険有害性の分類: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Self-heat. 1 - Skin Corr. 1B
• 補足的ハザード: EUH014,EUH019
• 保管分類コード: 4.2 - Pyrophoric and self-heating hazardous materials
• WGK: WGK 2
• 引火点(°F): 8.6 °F
• 引火点(℃): -13 °C