578932

N-アリル-N,N-ビス(トリメチルシリル)アミン

97%

• 別名: (Prop-2-en-1-yl)bis(trimethylsilyl)amine, 1,1,1-Trimethyl-N-2-propen-1-yl-N-(trimethylsilyl)silanamine, 3-Bis(trimethylsilyl)amino-1-propene, Bis(trimethylsilyl)allylamine, N,N-Bis(trimethylsilyl)-2-propen-1-amine, N,N-Bis(trimethylsilyl)allylamine, N-Allyl-1,1,1-trimethyl-N-(trimethylsilyl)silanamine
• 化学式: CH₂=CHCH₂NH[Si(CH₃)₃]₂
• CAS番号: 7688-51-9
• 分子量: 201.46
• EC Number: 231-699-2
• MDL番号: MFCD00545193
• UNSPSCコード: 12352103
• PubChem Substance ID: 24880960
• NACRES: NA.22

特性

• 品質水準: 100
• アッセイ: 97%
• 形状: liquid
• 屈折率: n20/D 1.440 (lit.)
• bp: 72 °C/15 mmHg (lit.)
• 密度: 0.816 g/mL at 25 °C (lit.)
• 官能基: amine
• SMILES記法: C[Si](C)(C)N(CC=C)[Si](C)(C)C
• InChI: 1S/C9H23NSi2/c1-8-9-10(11(2,3)4)12(5,6)7/h8H,1,9H2,2-7H3
• InChI Key: CVNCFZIIZGNVFD-UHFFFAOYSA-N

詳細

アプリケーション

N-Allyl-N,N-bis(trimethylsilyl)amine or N,N-bis(trimethylsilyl)prop-2-en-1-amine (AHMDS) can be used as a nucleophilic reagent to prepare:

• Complex bicyclic scaffolds by reacting with aryl aldehydes via imine formation followed by efficient multicomponent reactions.
• Dithiasuccinoyl (Dts) heterocycle by reacting with bisthiocarbamoyl chloride.
• Allyl selenide by reacting with aryl selenium salt in the presence of a ruthenium catalyst; Allyl selenide is utilized as a key intermediate in organic synthesis.

AHMDS can also be used as a reagent in hydrosilylation and hydroboration reaction. It may be also used as an electrolyte additive.

安全性情報

• ピクトグラム: GHS02,GHS07
• シグナルワード: Warning
• 危険有害性情報: H226,H315,H319,H335
• 注意書き: P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338
• 危険有害性の分類: Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
• ターゲットの組織: Respiratory system
• 保管分類コード: 3 - Flammable liquids
• WGK: WGK 3
• 引火点(°F): 109.0 °F - closed cup
• 引火点(℃): 42.78 °C - closed cup
• 個人用保護具 (PPE): Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter