すべての画像(1)
About This Item
化学式:
CH3OC10H6CO2H
CAS番号:
分子量:
202.21
MDL番号:
UNSPSCコード:
12352100
PubChem Substance ID:
NACRES:
NA.22
おすすめの製品
![Dichloro[(S,S)-ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium(IV)](/deepweb/assets/sigmaaldrich/product/structures/124/554/8e617376-6d1e-4ab5-af24-cd94f4ba26d3/640/8e617376-6d1e-4ab5-af24-cd94f4ba26d3.png)
![Tris[N,N-bis(trimethylsilyl)amide]yttrium](/deepweb/assets/sigmaaldrich/product/structures/867/983/5b7cb7cd-8879-49e4-a9d7-29c52aaa82a0/640/5b7cb7cd-8879-49e4-a9d7-29c52aaa82a0.png)
アッセイ
97%
mp
125-129 °C (lit.)
官能基
carboxylic acid
SMILES記法
COc1c(ccc2ccccc12)C(O)=O
InChI
1S/C12H10O3/c1-15-11-9-5-3-2-4-8(9)6-7-10(11)12(13)14/h2-7H,1H3,(H,13,14)
InChI Key
PMJACRPIWSINFF-UHFFFAOYSA-N
詳細
1-Methoxy-2-naphthoic acid can be prepared from 1-methoxynaphthalene.[1] 1-Methoxy-2-naphthoic acid can also be synthesized by reacting potassium tert-butoxide with 1-methoxynaphthalene and butyllithium in the presence of cyclohexane and tetrahydrofuran.[2] It undergoes reduction in the presence of lithium to afford tetrahydronaphthoic acid.[3]
アプリケーション
1-Methoxy-2-naphthoic acid may be used in the synthesis of 2-(1-methoxy-2-naphthyl)-4,4-dimethyl-2-oxazoline.[1] It may also be used in the synthesis of the following compounds:[4]
- 1-sec-butyl-2-naphthoic acid
- 1-tert-butyl-2-naphthoic acid
- 1-ethyl-2-naphthoic acid
- 1-vinyl-2-naphthoic acid
- 1-phenyl-2-naphthoic acid
- 1-(2,5-dimethylphenyl)-2-naphthoic acid
- 2′-methoxy-[1,1′-binaphthalene]-2-carboxylic acid
保管分類コード
11 - Combustible Solids
WGK
WGK 3
引火点(°F)
Not applicable
引火点(℃)
Not applicable
個人用保護具 (PPE)
Eyeshields, Gloves, type N95 (US)
適用法令
試験研究用途を考慮した関連法令を主に挙げております。化学物質以外については、一部の情報のみ提供しています。 製品を安全かつ合法的に使用することは、使用者の義務です。最新情報により修正される場合があります。WEBの反映には時間を要することがあるため、適宜SDSをご参照ください。
Jan Code
529133-1G:
529133-5G:
529133-VAR:
529133-BULK:
Eva Castagnetti et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 8(4), 799-804 (2002-02-22)
Judged by its capacity to promote a hydrogen/metal permutation at an ortho position, the trifluoromethoxy group is superior to both the methoxy and trifluoromethyl groups. Moreover, like CF(3) and unlike OCH(3), OCF(3) exerts a long-range effect that still considerably lowers
The metalation of 1-methoxynaphthalene with n-butyllithium.
Graybill BM and Shirley DA.
The Journal of Organic Chemistry, 31(4), 1221-1225 (1966)
Chemistry of aryloxazolines. Applications to the synthesis of lignan lactone derivatives.
Meyers AI and Avila WB.
The Journal of Organic Chemistry, 46(19), 3881-3886 (1981)
Birch Reduction of 2-Naphthoic and of ortho-Methoxynaphthoic Acids.
Eliel EL and Hoover TE.
The Journal of Organic Chemistry, 24(7), 938-942 (1959)
Regadia Aissaoui et al.
The Journal of organic chemistry, 77(1), 718-724 (2011-11-24)
Substitution of an ortho-fluoro or methoxy group in 1- and 2-naphthoic acids furnishing substituted naphthoic acids occurs in good to excellent yields upon reaction with alkyl/vinyl/aryl organolithium and Grignard reagents, in the absence of a metal catalyst without the need
アクティブなフィルタ
ライフサイエンス、有機合成、材料科学、クロマトグラフィー、分析など、あらゆる分野の研究に経験のあるメンバーがおります。.
製品に関するお問い合わせはこちら（テクニカルサービス）
