461075

1-(トリメチルシリル)-2-ピロリジノン

96%

• 実験式（ヒル表記法）: C₇H₁₅NOSi
• CAS番号: 14468-90-7
• 分子量: 157.29
• EC Number: 238-461-7
• MDL番号: MFCD00051572
• UNSPSCコード: 12352100
• PubChem Substance ID: 24869802
• NACRES: NA.22

特性

• アッセイ: 96%
• 屈折率: n20/D 1.46 (lit.)
• bp: 90 °C/20 mmHg (lit.)
• 密度: 0.983 g/mL at 25 °C (lit.)
• SMILES記法: C[Si](C)(C)N1CCCC1=O
• InChI: 1S/C7H15NOSi/c1-10(2,3)8-6-4-5-7(8)9/h4-6H2,1-3H3
• InChI Key: LUBVCBITQHEVCJ-UHFFFAOYSA-N

詳細

詳細

1-(Trimethylsilyl)-2-pyrrolidinone has been prepared by refluxing a mixture of 2-pyrrolidinone, triethylamine and trimethylchlorosilane in benzene. It undergoes sulfenylation with phenyl disulfide to form the corresponding bissulfide as the major product.

アプリケーション

1-(Trimethylsilyl)-2-pyrrolidinone may be used for the preparation of 1-(diphenylphosphonio)pyrrolidin-2-one and 1-(1-adamantylcarbonyl)-2-pyrrolidinone.

安全性情報

• ピクトグラム: GHS02,GHS07
• シグナルワード: Warning
• 危険有害性情報: H226,H315,H319,H335
• 注意書き: P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338
• 危険有害性の分類: Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
• ターゲットの組織: Respiratory system
• 保管分類コード: 3 - Flammable liquids
• WGK: WGK 3
• 引火点(°F): 127.4 °F - closed cup
• 引火点(℃): 53 °C - closed cup
• 個人用保護具 (PPE): Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter