412015

3-ブロモ-4-メトキシベンズアルデヒド

98%

• 別名: 3-ブロモ-p-アニスアルデヒド
• 化学式: BrC₆H₃(OCH₃)CHO
• CAS番号: 34841-06-0
• 分子量: 215.04
• EC Number: 252-241-8
• MDL番号: MFCD00016599
• UNSPSCコード: 12352100
• PubChem Substance ID: 24865781
• NACRES: NA.22

特性

• アッセイ: 98%
• mp: 51-54 °C (lit.)
• SMILES記法: COc1ccc(C=O)cc1Br
• InChI: 1S/C8H7BrO2/c1-11-8-3-2-6(5-10)4-7(8)9/h2-5H,1H3
• InChI Key: QMPNFQLVIGPNEI-UHFFFAOYSA-N

詳細

詳細

3-Bromo-4-methoxybenzaldehyde is formed by the solvent-free bromination of 4-methoxybenzaldehyde using 1,3-di-n-butylimidazolium tribromide, as a brominating reagent.[1]

アプリケーション

3-Bromo-4-methoxybenzaldehyde may be used in the following studies:

• Asymmetric synthesis of a novel β-hydroxy-α-amino acid derivative, via Mukaiyama aldol reaction.[2]
• Synthesis of 2-(3-bromo-4-methoxyphenyl)-5-fluorobenzothiazole.[3]
• Preparation of 5-[(Z)-2-(3-bromo-4-methoxyphenyl)vinyl]-1,2-3-trimethoxybenzene.[4]
• Total synthesis of engelhardione.[5]
• Starting reagent for the synthesis of (2E)-3-(3-bromo-4-methoxyphenyl)-1-(4-methylphenyl)prop-2-en-1-one.[6]

安全性情報

• 保管分類コード: 13 - Non Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable
• 個人用保護具 (PPE): Eyeshields, Gloves, type N95 (US)