401595

4-(ジフェニルホスフィノ)安息香酸

97%

• 別名: (4-カルボキシフェニル)ジフェニルホスフィン, p-(ジフェニルホスフィノ)安息香酸, ジフェニル(p-カルボキシフェニル) ホスフィン
• 化学式: (C₆H₅)₂PC₆H₄CO₂H
• CAS番号: 2129-31-9
• 分子量: 306.30
• MDL番号: MFCD00407264
• UNSPSCコード: 12352002
• PubChem Substance ID: 24865028
• NACRES: NA.22

特性

• アッセイ: 97%
• 反応適合性: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand
• mp: 157-160 °C (lit.)
• 官能基: phosphine
• SMILES記法: OC(=O)c1ccc(cc1)P(c2ccccc2)c3ccccc3
• InChI: 1S/C19H15O2P/c20-19(21)15-11-13-18(14-12-15)22(16-7-3-1-4-8-16)17-9-5-2-6-10-17/h1-14H,(H,20,21)
• InChI Key: GXMHDTPYKRTARV-UHFFFAOYSA-N

詳細

詳細

4-(Diphenylphosphino)benzoic acid is a phosphine ligand that is employed in palladium-catalyzed cross-coupling and Suzuki cross-coupling reactions.

アプリケーション

4-(Diphenylphosphino)benzoic acid can be used as a ligand in the synthesis of:

• Organostannoxane-supported palladium nanoparticles. The resulting catalysts show high activity and selectivity in Suzuki-coupling reactions.
• Polymetallic ruthenium-zinc complex catalyst for the hydrogenation of levulinic acid to γ-valerolactone.

安全性情報

• ピクトグラム: GHS07
• シグナルワード: Warning
• 危険有害性情報: H315,H319,H335
• 注意書き: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危険有害性の分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• ターゲットの組織: Respiratory system
• 保管分類コード: 11 - Combustible Solids
• WGK: WGK 3
• 個人用保護具 (PPE): dust mask type N95 (US), Eyeshields, Gloves