388076

tert-Butyl peracetate solution

50 wt. % in odorless mineral spirits

• 別名: tert -Butyl peracetate, tert -Butyl peroxyacetate
• 化学式: CH₃CO₃C(CH₃)₃
• CAS番号: 107-71-1
• 分子量: 132.16
• MDL番号: MFCD00048240
• UNSPSCコード: 12162002
• PubChem Substance ID: 24864203
• NACRES: NA.23

特性

• フォーム: liquid
• t1/2: 10 hr(101 °C, 0.2 M in benzene)
• 濃度: 50 wt. % in odorless mineral spirits
• 屈折率: n20/D 1.412
• 密度: 0.828 g/mL at 25 °C
• SMILES記法: CC(=O)OOC(C)(C)C
• InChI: 1S/C6H12O3/c1-5(7)8-9-6(2,3)4/h1-4H3
• InChI Key: SWAXTRYEYUTSAP-UHFFFAOYSA-N

詳細

アプリケーション

Allows the direct copper catalyzed acetoxylation of β-lactams at the 4-position.[1]

Reagent used as a methyl-radical source under photoredox catalysis in conjunction with photocatalyst [Ir{dF(CF₃)ppy}₂(dtbpy)]PF₆ (Aldrich L511765) for late-stage functionalization of biologically active heterocycles.

Late-Stage Functionalization of Biologically Active Heterocycles Through Photoredox Catalysis

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

安全性情報

• ピクトグラム: GHS02,GHS08,GHS07
• シグナルワード: Danger
• 危険有害性情報: H226,H242,H302,H304,H315,H319,H335,H336,H340,H350
• 注意書き: P210 - P280 - P301 + P310 - P331 - P370 + P378 - P403 + P235
• 危険有害性の分類: Acute Tox. 4 Oral - Asp. Tox. 1 - Carc. 1B - Eye Irrit. 2 - Flam. Liq. 3 - Muta. 1B - Org. Perox. C - Skin Irrit. 2 - STOT SE 3
• ターゲットの組織: Central nervous system, Respiratory system
• 保管分類コード: 5.2 - Organic peroxides and self-reacting hazardous materials
• WGK: WGK 3
• 引火点(°F): 98.6 °F - closed cup
• 引火点(℃): 37 °C - closed cup
• 個人用保護具 (PPE): Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter