380768

ジフェニルリン化カリウム 溶液

0.5 M in THF

• 別名: カリウム ジフェニルホスフィン, KPPh₂, ジフェニルホスフィン カリウム塩
• 化学式: (C₆H₅)₂PK
• CAS番号: 15475-27-1
• 分子量: 224.28
• Beilstein: 4164304
• MDL番号: MFCD00134530
• UNSPSCコード: 12352002
• PubChem Substance ID: 24863767
• NACRES: NA.22

特性

• 形状: liquid
• 反応適合性: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand
• 濃度: 0.5 M in THF
• 密度: 0.929 g/mL at 25 °C
• 官能基: phosphine
• SMILES記法: [K]P(c1ccccc1)c2ccccc2
• InChI: 1S/C12H10P.K/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10H;/q-1;+1
• InChI Key: FCLYZQXPJKJTDR-UHFFFAOYSA-N

詳細

アプリケーション

• Synthesis, reactivity and molecular structure of phosphino tetramethyl cyclopentadienyl complex (eta5: eta1-C5Me4CH2PPh2)Re(CO)2.: This study explores the synthesis and reactivity of a novel phosphino complex, utilizing Potassium diphenylphosphide as a key reagent. The research highlights the molecular structure and potential applications in organometallic chemistry (Godoy et al., 2009).


• Improved and efficient synthesis of chiral N,P-ligands via cyclic sulfamidates for asymmetric addition of butyllithium to benzaldehyde.: This paper details an improved synthesis method for chiral N,P-ligands using Potassium diphenylphosphide. The research demonstrates the compound′s efficacy in asymmetric synthesis, offering potential advancements in drug discovery and development (Rönnholm et al., 2007).


• Coordination chemistry of diselenophosphinate complexes: the X-ray single-crystal structures of [K(Se2PPh2)(THF)2]2 and [In(Se2PPh2)3].L (L = THF, PhMe).: This article investigates the coordination chemistry involving diselenophosphinate complexes, with Potassium diphenylphosphide playing a crucial role. The study provides detailed X-ray crystallographic data, offering insights for future research in chemical synthesis and materials science (Davies et al., 2004).

安全性情報

• ピクトグラム: GHS02,GHS08,GHS05,GHS07
• シグナルワード: Danger
• 危険有害性情報: H225,H302,H314,H335,H351
• 注意書き: P201 - P210 - P233 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• 危険有害性の分類: Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
• ターゲットの組織: Respiratory system
• 補足的ハザード: EUH018,EUH019
• 保管分類コード: 3 - Flammable liquids
• WGK: WGK 3
• 引火点(°F): -4.0 °F - closed cup
• 引火点(℃): -20 °C - closed cup
• 個人用保護具 (PPE): Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter