345482

Methyl (R)-(+)-2,2-dimethyl-1,3-dioxolane-4-carboxylate

98%

• 別名: α,β-Isopropylidene-D-glyceric acid methyl ester, Methyl α,β-isopropylidene-D-glycerate, Methyl 2,3-O-isopropylidene-D-glycerate
• 実験式（ヒル表記法）: C₇H₁₂O₄
• CAS番号: 52373-72-5
• 分子量: 160.17
• Beilstein: 4292353
• MDL番号: MFCD00066527
• UNSPSCコード: 12352005
• PubChem Substance ID: 24861325
• NACRES: NA.22

特性

• 品質水準: 200
• アッセイ: 98%
• フォーム: liquid
• 光学活性: [α]20/D +8.5°, c = 1.5 in acetone
• 屈折率: n20/D 1.426 (lit.)
• bp: 70-75 °C/10 mmHg (lit.)
• 密度: 1.106 g/mL at 25 °C (lit.)
• 官能基: ester; ether; ketal
• SMILES記法: COC(=O)[C@H]1COC(C)(C)O1
• InChI: 1S/C7H12O4/c1-7(2)10-4-5(11-7)6(8)9-3/h5H,4H2,1-3H3/t5-/m1/s1
• InChI Key: DOWWCCDWPKGNGX-RXMQYKEDSA-N

詳細

アプリケーション

Methyl (R)-(+)-2,2-dimethyl-1,3-dioxolane-4-carboxylate may be used as a starting material to synthesize (2R)-[1-²H₂]-glycerol, a probe to study the stereochemistry of glycerol metabolism in Streptomyces cattleya.[1] It may also be used to synthesize organic building blocks like (R)-2,3-dihydroxy-3-methylbutyl toluene-p-sulfonate[2] and (2S,8R)-2-amino-8-[(R) 2,2-dimethyl-1,3-dioxolan-4-yl]-8-oxooctanoic acid.[3]

安全性情報

• 保管分類コード: 10 - Combustible liquids
• WGK: WGK 3
• 引火点(°F): 167.0 °F - closed cup
• 引火点(℃): 75 °C - closed cup
• 個人用保護具 (PPE): Eyeshields, Gloves, type ABEK (EN14387) respirator filter