332364

アリルトリフェニルスタンナン

97%

• 別名: 2-プロペニル-トリフェニルスタンナン, アリルトリフェニルスズ
• 化学式: CH₂=CHCH₂Sn(C₆H₅)₃
• CAS番号: 76-63-1
• 分子量: 391.09
• Beilstein: 3612762
• EC Number: 200-975-4
• MDL番号: MFCD00048162
• UNSPSCコード: 12352103
• PubChem Substance ID: 24859890
• NACRES: NA.22

特性

• アッセイ: 97%
• フォーム: solid
• mp: 71-74 °C (lit.)
• SMILES記法: C=CC[Sn](c1ccccc1)(c2ccccc2)c3ccccc3
• InChI: 1S/3C6H5.C3H5.Sn/c3*1-2-4-6-5-3-1;1-3-2;/h3*1-5H;3H,1-2H2;
• InChI Key: NDUYAGLANMHJHF-UHFFFAOYSA-N

詳細

詳細

Allyltriphenylstannane is an organotin compound, which is generally used as allylating and radical chain transfer reagent. It is also used as a source of allyl radicals.[1]

アプリケーション

Allyltriphenylstannane can be used:

• As a reagent in the C-H phenylation of azoles catalyzed by palladium.[2]
• As an allylating reagent in the alkylidene Meldrum′s acids allylation catalyzed by Sc(OTf)₃.[3]
• As a reagent in the total synthesis of an antifungal molecule (+)-ambruticin S.[4]

安全性情報

• ピクトグラム: GHS06,GHS09
• シグナルワード: Danger
• 危険有害性情報: H301 + H311 + H331,H410
• 注意書き: P261 - P273 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311
• 危険有害性の分類: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1
• 保管分類コード: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable
• 個人用保護具 (PPE): Eyeshields, Gloves, type N95 (US)