233161

3′-(トリフルオロメチル)アセトフェノン

99%

• 別名: 3-アセチルベンゾトリフルオリド
• 化学式: CF₃C₆H₄COCH₃
• CAS番号: 349-76-8
• 分子量: 188.15
• Beilstein: 640151
• EC Number: 206-490-4
• MDL番号: MFCD00000391
• UNSPSCコード: 12352100
• PubChem Substance ID: 24853957
• NACRES: NA.22

特性

• アッセイ: 99%
• 形状: liquid
• 屈折率: n20/D 1.4611 (lit.)
• bp: 198-200 °C (lit.)
• 密度: 1.235 g/mL at 25 °C (lit.)
• SMILES記法: CC(=O)c1cccc(c1)C(F)(F)F
• InChI: 1S/C9H7F3O/c1-6(13)7-3-2-4-8(5-7)9(10,11)12/h2-5H,1H3
• InChI Key: ABXGMGUHGLQMAW-UHFFFAOYSA-N

詳細

詳細

Asymmetric catalytic addition of ethyl groups to 3′-(trifluoromethyl)acetophenone catalyzed by ligands derived from trans-1,2-diaminocyclohexane and camphor sulfonyl chloride has been reported. Phenylation of 3′-(trifluoromethyl)acetophenone in the presence of dihydroxy bis(sulfonamide) ligand (enantioselective catalyst), titanium tetraisopropoxide and diphenylzinc has been investigated.

アプリケーション

3′-(Trifluoromethyl)acetophenone has been used in a key step during the preparation of a commercial fungicide.

安全性情報

• ピクトグラム: GHS07
• シグナルワード: Warning
• 危険有害性情報: H315,H319,H335
• 注意書き: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危険有害性の分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• ターゲットの組織: Respiratory system
• 保管分類コード: 10 - Combustible liquids
• WGK: WGK 1
• 引火点(°F): 174.2 °F - closed cup
• 引火点(℃): 79 °C - closed cup
• 個人用保護具 (PPE): Eyeshields, Gloves, type ABEK (EN14387) respirator filter