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10609

Sigma-Aldrich

9-Anthracenecarbonyl cyanide

BioReagent, suitable for fluorescence, ≥98.5% (GC)

Sinonimo/i:

α-Oxo-anthracene-9-acetonitrile, 9-Anthroyl nitrile

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About This Item

Formula empirica (notazione di Hill):
C16H9NO
Numero CAS:
85985-44-0
Peso molecolare:
231.25
Beilstein:
8145431
Numero MDL:
MFCD00467599
Codice UNSPSC:
12352108
ID PubChem:
329748910
NACRES:
NA.32

Nome Commerciale

BioReagent

Saggio

≥98.5% (GC)

Forma fisica

solid

Punto di fusione

142-143 °C (lit.)

Solubilità

DMF: soluble
acetonitrile: soluble
chloroform: soluble

Fluorescenza

λex 361 nm; λem 451 nm (after derivatization with ethanol)
λex 361 nm; λem 460 nm in methanol

Compatibilità

suitable for fluorescence

Temperatura di conservazione

−20°C

Stringa SMILE

O=C(C#N)c1c2ccccc2cc3ccccc13

InChI

1S/C16H9NO/c17-10-15(18)16-13-7-3-1-5-11(13)9-12-6-2-4-8-14(12)16/h1-9H
FMKFDGUBVPIERQ-UHFFFAOYSA-N

Applicazioni

9-Anthroyl nitrile is a fluorescent reagent useful in the derivatization of glucocorticoids to aid their detection and separation using RP-HPLC with fluorescence detection. It forms fluorescent esters by reacting with primary the hydroxyl group at the position 21 of the carbon chain on the glucocorticoid .

Confezionamento

Bottomless glass bottle. Contents are inside inserted fused cone.

Altre note

For derivatization of hydroxyl compounds for HPLC with fluorescence detection.

Pittogrammi

Exclamation mark
GHS07

Avvertenze

Warning

Indicazioni di pericolo

H302 + H312 + H332

Classi di pericolo

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

dust mask type N95 (US), Eyeshields, Gloves

Certificati d'analisi (COA)

Cerca il Certificati d'analisi (COA) digitando il numero di lotto/batch corrispondente. I numeri di lotto o di batch sono stampati sull'etichetta dei prodotti dopo la parola ‘Lotto’ o ‘Batch’.

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E Neufeld et al.
Journal of chromatography. B, Biomedical sciences and applications, 718(2), 273-277 (1998-12-05)
Corticosteroids containing a C21 primary hydroxyl group were derivatised with 9-anthroyl cyanide. The reagent was prepared as a solution in acetonitrile, containing 0.1% triethylamine, at a concentration of 2 mg/ml. Approximately 1 microg of corticosteroid was reacted with 100 microl
D A Owensby et al.
The Journal of biological chemistry, 264(30), 18180-18187 (1989-10-25)
Hepatic parenchymal cells contribute to the clearance of circulating tissue-type plasminogen activator (t-PA) in vivo. The hepatocyte extracellular matrix is interposed between the endothelial-lined sinusoids and the parenchymal cell surface and thus may influence t-PA clearance. To test this hypothesis
Thomas J Nelson
Analytical biochemistry, 419(1), 40-45 (2011-08-30)
A new ultrasensitive fluorescent derivatization procedure for chromatographic analysis of primary, secondary, and nonpolar tertiary alcohols is described. The procedure uses Bodipy FL in basic dichloromethane solution with Mukaiyama's reagent (2-chloro-1-methylpyridinium iodide) to form highly fluorescent ester derivatives that can
J. Goto et al.
Analytica Chimica Acta, 147, 397-397 (1983)
Y Saisho et al.
Analytical biochemistry, 252(1), 89-95 (1997-11-05)
A nonradioisotopic method has been developed for the determination of all-trans-farnesyl pyrophosphate (FPP), the common intermediate at the branch point of the biosynthesis of cholesterol and nonsterol end products, in dog and human plasma. FPP was cleaved to the parent
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