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443808

Sigma-Aldrich

ter-butil metil etere

ACS reagent, ≥99.0%

Sinonimo/i:

MTBE, Metil ter-butil etere

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About This Item

Formula condensata:
(CH3)3COCH3
Numero CAS:
Peso molecolare:
88.15
Beilstein:
1730942
Numero CE:
Numero MDL:
Codice UNSPSC:
12352112
ID PubChem:
NACRES:
NA.07

Grado

ACS reagent

Livello qualitativo

Densità del vapore

3.1 (vs air)

Tensione di vapore

4.05 psi

Saggio

≥99.0%

Forma fisica

liquid

Temp. autoaccensione

705 °F

Limite di esplosione

15.1 %

Impurezze

≤0.05% water
<1 ppm H2O2

Residuo dopo evaporazione

≤0.001%

Colore

APHA: ≤10

Indice di rifrazione

n20/D 1.369 (lit.)

P. eboll.

55-56 °C (lit.)

Punto di fusione

-110 °C

Densità

0.74 g/mL at 25 °C (lit.)

applicazioni

microbiology

Stringa SMILE

COC(C)(C)C

InChI

1S/C5H12O/c1-5(2,3)6-4/h1-4H3
BZLVMXJERCGZMT-UHFFFAOYSA-N

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Descrizione generale

tert-Butyl methyl ether (methyl tert-butyl ether, MTBE) is a gasoline additive. Its oxidative degradation by propane-oxidizing bacterial strains has been tested. Kinetics of its heat-mediated biodegradation has been investigated under various reaction conditions. Its biodegradation followed a pseudo-first-order decay model and its pseudo-first-order rate constants were evaluated. Its extraction from water has been proposed by employing an organic polymeric compound, Nafion. MTBE can be synthesized by acid-catalyzed reaction between methanol and isobutene. A study suggests that the addition of MTBE increases the number of active sites during polymerization of propene by stopped-flow method. This solvent meets ACS (American Chemical Society) specifications and can be used for processes requiring strict quality conditions such as analytical testing.

Applicazioni

tert-Butyl methyl ether (methyl tert-butyl ether, MTBE) may be used:
  • As sole carbon and energy source in a mixed microbial consortium.
  • To extract lipids from biological fluids for shotgun profiling.
  • To synthesize fatty acid methyl esters (FAMEs) and glycerol tert-butyl ether by transesterification of canola oil in the absence of catalyst under supercritical condition.

Pittogrammi

FlameExclamation mark

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Flam. Liq. 2 - Skin Irrit. 2

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 1

Punto d’infiammabilità (°F)

-18.4 °F - closed cup

Punto d’infiammabilità (°C)

-28 °C - closed cup


Certificati d'analisi (COA)

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I clienti hanno visto anche

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1 of 1

Lipid extraction by methyl-tert-butyl ether for high-throughput lipidomics.
Matyash V, et al.
Journal of Lipid Research, 49(5), 1137-1146 (2008)
Removal of methyl tert-butyl ether (MTBE) with Nafion.
Lien HL and Zhang WX
Journal of Hazardous Materials, 144(1), 194-199 (2007)
New approach of catalyst-free biodiesel production from canola oil in supercritical tert-butyl methyl ether (MTBE).
Farobie O, et al.
Fuel: The Science and Technology of Fuel and Energy, 135, 172-181 (2014)
Eagleson M.
Concise Encyclopedia Chemistry, 154-154 (1994)
Role of tert-Butyl Methyl Ether (TBME) as an External Donor in Propene Polymerization with Dibutyl Phthalate (DBP)-Containing MgCl2-Supported Ti Catalysts Activated with Al(i-C4H9)3.
Ohnishi R and Konakazawa T.
Macromolecular Chemistry and Physics, 205(14), 1938-1947 (2004)

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