383074

Bismuth(III) nitrate pentahydrate

ACS reagent, ≥98.0%

• Formula condensata: Bi(NO₃)₃ · 5H₂O
• Numero CAS: 10035-06-0
• Peso molecolare: 485.07
• Numero CE: 233-791-8
• Codice UNSPSC: 12352302
• ID PubChem: 24863932
• NACRES: NB.24
• Saggio: ≥98.0%
• Grado: ACS reagent
• Stato: (Powder or Crystals or Solid or Chunks)

Proprietà

• Grado: ACS reagent
• Livello qualitativo: 200
• Saggio: ≥98.0%
• Stato: (Powder or Crystals or Solid or Chunks)
• Impiego in reazioni chimiche: reagent type: catalyst; core: bismuth
• Impurezze: ≤0.005% insolubles
• P. ebollizione: 75-80 °C (lit.)
• Punto di fusione: 30 °C (lit.)
• Anioni in tracce: chloride (Cl^-): ≤0.001%; sulfate (SO₄^2-): ≤0.005%
• Cationi in tracce: Ag: ≤0.001%; As: ≤0.001%; Ca: ≤0.005%; Cu: ≤0.002%; Fe: ≤0.001%; K: ≤0.01%; Na: ≤0.02%; Pb: ≤0.002%
• Stringa SMILE: O=[N+](O[Bi](O[N+]([O-])=O)O[N+]([O-])=O)[O-].C
• InChI: 1S/CH4.Bi.3NO3/c;;3*2-1(3)4/h1H4;;;;/q;+3;3*-1; DPLOIMSBRDLLRI-UHFFFAOYSA-N

Descrizione

Descrizione generale

Bismuth(III) nitrate pentahydrate is a non-toxic, inexpensive, easy to handle and air insensitive reagent, commonly used in organic synthesis with a wide range of applications.[1]

Applicazioni

Bismuth(III) nitrate pentahydrate may be used in the following processes:

• Conversion of thioamides and thioureas to their oxo derivatives.[2]
• Transformation of aromatic aldehydes to carboxylic acids under microwave and solvent free conditions.[3]
• Synthesize coumarins by Pechmann condensation under solvent free conditions.[1]
• As a precursor in the synthesis of pure and lanthanum-modified bismuth ferrite (BFO) ceramics.[4]
• As a nitrating agent in the synthesis of methyl nitramino-2,4,6-trinitrobenzenes under microwave irradiation.[5]
• As a catalyst in the preparation of 4-amino-5-pyrimidine carbonitrile and pyrimidinone derivatives.[6]
• Synthesis of glycosides by Fischer glycosylation of unprotected sugars.[7]
• Synthesis of bismuth oxide (Bi₂O₃) nanoparticles.[8]
• Oxidation of 4-substituted Hantzsch 1,4-dihydropyridines.[9]
• Selective oxidation of sufides to sulfoxides.[10]

Informazioni sulla sicurezza

• Pittogrammi: GHS03,GHS05
• Avvertenze: Danger
• Indicazioni di pericolo: H272,H318
• Consigli di prudenza: P210 - P220 - P280 - P305 + P351 + P338 - P370 + P378 - P501
• Classi di pericolo: Eye Dam. 1 - Ox. Sol. 2
• Codice della classe di stoccaggio: 5.1B - Oxidizing hazardous materials
• Classe di pericolosità dell'acqua (WGK): WGK 2
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable