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Supelco

Hydrogen chloride solution

~3 M in 1-butanol, for GC derivatization, LiChropur™

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About This Item

Numero CAS:
7647-01-0
Beilstein:
1098214
Numero MDL:
MFCD00011324
Codice UNSPSC:
12352301
ID PubChem:
329769583
NACRES:
NA.22

product name

Hydrogen chloride - 1-butanol solution, ~3 M in 1-butanol, for GC derivatization, LiChropur™

Grado

for GC derivatization

Livello qualitativo

100

Forma fisica

solution

Qualità

LiChropur™

Impiego in reazioni chimiche

reagent type: derivatization reagent
reaction type: Acylations

Concentrazione

~3 M in 1-butanol

tecniche

gas chromatography (GC): suitable

Densità

0.87 g/mL at 20 °C

Temperatura di conservazione

2-8°C

Stringa SMILE

Cl

InChI

1S/ClH/h1H
VEXZGXHMUGYJMC-UHFFFAOYSA-N

Categorie correlate

Descrizione generale

Acylation, an alternative to silylation, is the conversion of compounds that contain active hydrogens (-OH, -SH and -NH) into esters, thioesters, and amides through the action of a carboxylic acid or derivative. The presence of a carbonyl group adjacent to the halogenated carbons enhances electron capture detector (ECD) response. Acylation has many benefits:
  • It improves the stability of compounds by protecting unstable groups.
  • It may confer volatility on substances such as carbohydrates or amino acids, which have so many polar groups that they are non-volatile and normally decompose on heating.
  • It assists in separations not possible with underivatized compounds.
  • Compounds are detectable at very low levels with an ECD.

Hydrogen chloride-1-butanol is a reagent utilized to form fragmentation-directing derivatives for GC/MS analysis.

Applicazioni

Hydrogen chloride - 1-butanol solution has been used for butylation of amino acids during blood sample analysis for determination of ethylenediaminetetraacetic acid using mass spectrometry.

Altre note

Reagent for the esterification of amino acids and carnites for GC-MS analysis

Note legali

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Avvertenze

Danger

Indicazioni di pericolo

H226,H290,H302,H315,H318,H335,H336

Classi di pericolo

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Met. Corr. 1 - Skin Irrit. 2 - STOT SE 3

Organi bersaglio

Respiratory system

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 1

Dispositivi di protezione individuale

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Elenchi normativi

Forniamo informazioni su eventuali restrizioni prevalentemente per i prodotti chimici. Per altre tipologie di prodotto siamo in grado di fornire soltanto informazioni limitate. Nessuna segnalazione significa che nessuno dei componenti è citato in un elenco. È dovere dell’utilizzatore assicurarsi che il prodotto venga impiegato in maniera sicura e a norme di legge.

EU REACH Annex XVII (Restriction List)

CAS No.

Choose from one of the most recent versions:

Certificati d'analisi (COA)

Lot/Batch Number
BCCL8269
BCCJ6881
BCCG8459
BCCF1421
BCCC2214

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1-butanolo anhydrous, 99.8%

Sigma-Aldrich

281549

1-butanolo

Cloruro di idrogeno 1.0 M in diethyl ether

Sigma-Aldrich

294837

Cloruro di idrogeno

Acido acetico for LC-MS LiChropur™

Supelco

5.33001

Acido acetico

1-butanolo suitable for HPLC, ≥99.7%

Sigma-Aldrich

34867

1-butanolo

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Q Miao et al.
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The pectic polysaccharide named abienan AS-A was isolated from the wood greenery of Abies sibirica using dilute hydrochloric acid (pH 4.0) at 70°C. The structure of abienan AS-A was elucidated using sugar composition analysis, ion-exchange chromatography and partial acid hydrolysis
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