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Sigma-Aldrich

Sodium methoxide solution

25 wt. % in methanol

Sinonimo/i:

Sodium methylate

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About This Item

Formula condensata:
CH3ONa
Numero CAS:
124-41-4
Peso molecolare:
54.02
Beilstein:
3592982
Numero MDL:
MFCD00012179
Codice UNSPSC:
12352100
ID PubChem:
24849600
NACRES:
NA.21

Densità del vapore

1.1 (vs air)

Livello qualitativo

200

Tensione di vapore

50 mmHg ( 20 °C)
96 mmHg ( 25 °C)

Forma fisica

liquid

Temp. autoaccensione

878 °F

Concentrazione

25 wt. % in methanol

Indice di rifrazione

n20/D 1.37

Densità

0.945 g/mL at 25 °C

Stringa SMILE

[Na+].C[O-]

InChI

1S/CH3O.Na/c1-2;/h1H3;/q-1;+1
WQDUMFSSJAZKTM-UHFFFAOYSA-N

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Categorie correlate

Descrizione generale

The product is 25wt.% solution of sodium methoxide in methanol. Its reaction with unactivated aryl bromides in the presence of copper catalyst under various reaction conditions has been studied. It reacts with aryl halides in the presence of a palladium catalyst in DMF (Dimethylformamide) to afford arenes.

Applicazioni

A novel high-spin hexanuclear Mn(III) cluster, [NaMn6(OMe)12(dbm)6]+, was synthesized via MnCl2 oxidation with simultaneous NaOMe promoted aggregation. This cluster has an unprecedented cyclic structure and 24 unpaired electrons in its ground state.
Sodium methoxide solution has been used in the synthesis of NO-containing nanoparticles (SNO-NP).

Avvertenze

Danger

Classi di pericolo

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Corr. 1A - STOT SE 1

Organi bersaglio

Eyes,Central nervous system

Rischi supp

EUH014

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 2

Punto d’infiammabilità (°F)

60.0 °F - closed cup - Solvent

Punto d’infiammabilità (°C)

15.55 °C - closed cup - Solvent

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Certificati d'analisi (COA)

Lot/Batch Number
SHBR7164
BCCM2931
BCCK3620
BCCK3618
SHBR0352

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