The journal of physical chemistry. A, 109(45), 10451-10458 (2006-07-13)
Various molecular species are known to form during the photoreaction of C2H4I2 in the gas phase and in solution. We have studied all species involved in this reaction by ab initio and density functional theory (DFT) calculations: Geometries, energies, and
Langmuir : the ACS journal of surfaces and colloids, 24(18), 9974-9978 (2008-08-21)
This study presents a method to measure the contact angles of oils on a substrate in water. Diiodomethane and perfluorodecalin were used as model oils. Self-assembled monolayers (SAMs) were prepared by adjusting the mole ratio of CH 3- and OH-terminated
Science (New York, N.Y.), 309(5738), 1223-1227 (2005-07-16)
We report direct structural evidence of the bridged radical (CH2ICH2.) in a polar solution, obtained using time-resolved liquid-phase x-ray diffraction. This transient intermediate has long been hypothesized to explain stereo-chemical control in many association and/or dissociation reactions involving haloalkanes. Ultrashort
Colloids and surfaces. B, Biointerfaces, 75(2), 550-556 (2009-10-24)
The self-assembled monolayers (SAMs) with gradient surface free energies were prepared by surface grafting of a binary mixture of methyl and vinyl terminated trimethoxysilanes on hydrophilic glass slides followed by in situ oxidation of vinyl groups into carboxyl groups. Characterized
Colloids and surfaces. B, Biointerfaces, 68(2), 238-244 (2008-12-26)
Wettability of biomaterials surfaces and protein-coated substrates is generally characterized with the sessile drop technique using polar and apolar liquids. This procedure is often performed in air, which does not reflect the physiological conditions. In this study, liquid/liquid contact angle
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