Passa al contenuto
Merck
Tutte le immagini(1)

Documenti fondamentali

ALD00444

Sigma-Aldrich

Late Stage Functionalization Toolkit

Sinonimo/i:

Baran Late-Stage Functionalization Kit, LSF Toolkit featuring Baran Diversinates

Autenticatiper visualizzare i prezzi riservati alla tua organizzazione & contrattuali


About This Item

Codice UNSPSC:
41116155
NACRES:
NA.22

Temperatura di conservazione

2-8°C

Applicazioni

The Baran Late-Stage Toolkit is a convenient collection of 12 highly innovative reagents that are highly effective in the diversification of complex molecules. The contents in the box are 11 Baran Diversinates and one vial of Palau′Chlor® in amounts of 100 mg each. For obtaining larger amounts of any desired kit component, see the kit component table at the bottom of the page.

Useful Topics:
Late Stage Functionalization

Baran Group – Professor Product Portal

Palau′Chlor
Diversinates

Note legali

Diversinates is a trademark of Sigma-Aldrich Co. LLC
Palau'Chlor is a registered trademark of Merck KGaA, Darmstadt, Germany

I componenti del kit sono disponibili anche separatamente

N° Catalogo
Descrizione
SDS

  • 745480Zinc isopropylsulfinate, 95%SDS

  • 745405Sodium 1,1-difluoroethanesulfinateSDS

  • 745499Zinc trifluoroethanesulfinateSDS

  • 767840Zinc difluoromethanesulfinate, 95%SDS

  • 771406Zinc trifluoromethanesulfinateSDS

  • ALD00288Sodium tert-butylsulfinateSDS

  • ALD00290Sodium 2,2-dimethylpropylsulfinateSDS

  • 792454Palau′Chlor®, 95%SDS

  • 790184Sodium 1-(trifluoromethyl)cyclopropanesulfinateSDS

  • 790796Zinc benzylsulfinateSDS

  • ALD00230Sodium 4,4-difluorocyclohexanesulfinateSDS

  • ALD00232Sodium tetrahydropyransulfinateSDS

Vedi tutto (12)

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

Organi bersaglio

Respiratory system

Codice della classe di stoccaggio

8A - Combustible corrosive hazardous materials


Scegli una delle versioni più recenti:

Certificati d'analisi (COA)

Lot/Batch Number

Ci dispiace, ma al momento non ci sono COA disponibili online per questo prodotto.

Se ti serve aiuto, non esitare a contattarci Servizio Clienti

Possiedi già questo prodotto?

I documenti relativi ai prodotti acquistati recentemente sono disponibili nell’Archivio dei documenti.

Visita l’Archivio dei documenti

Simple Sulfinate Synthesis Enables C-H Trifluoromethylcyclopropanation
Gianatassio R, et al.
Angewandte Chemie (International Edition in English), 53, 9851-9855 (2014)
Radical C?H Functionalization of Heteroarenes under Electrochemical Control.
O'Brien, et al.
Angewandte Chemie (International Edition in English), 53, 11868-11871 (2014)
A C?H Methylation Reaction of Heteroarenes Inspired by Radical SAM Methyl Transferase.
Gui J, et al.
Journal of the American Chemical Society, 136, 4853-4856 (2014)
Palau'chlor: A Practical and Reactive Chlorinating Reagent
Rodriguez RA, et al.
Journal of the American Chemical Society, 136, 6908-6911 (2014)
Yuta Fujiwara et al.
Journal of the American Chemical Society, 134(3), 1494-1497 (2012-01-11)
Molecular scaffolds containing alkylfluorine substituents are desired in many areas of chemical research from materials to pharmaceuticals. Herein, we report the invention of a new reagent (Zn(SO(2)CF(2)H)(2), DFMS) for the innate difluoromethylation of organic substrates via a radical process. This

Contenuto correlato

The Baran Group works with Sigma-Aldrich in providing a portfolio of zinc-based reagents promoting difluoromethylation, trifluoromethylation, trifluoroethylation and isopropylation of aryl and heteroaryl motifs. Baran’s lab has also helped introduce a portable desaturase (Tz0Cl), which promotes the installation of alcohol and amine groups and leaves behind a highly useful tosyl group for further transformations.

Il team dei nostri ricercatori vanta grande esperienza in tutte le aree della ricerca quali Life Science, scienza dei materiali, sintesi chimica, cromatografia, discipline analitiche, ecc..

Contatta l'Assistenza Tecnica.