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A88255

Sigma-Aldrich

p-Anisidine

99%

Sinonimo/i:

4-Aminoanisole, 4-Methoxyaniline

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About This Item

Formula condensata:
CH3OC6H4NH2
Numero CAS:
104-94-9
Peso molecolare:
123.15
Beilstein:
471556
Numero MDL:
MFCD00007864
Codice UNSPSC:
12352100
ID PubChem:
24891372
NACRES:
NA.22

Livello qualitativo

200

Saggio

99%

Forma fisica

solid

Temp. autoaccensione

959 °F

P. eboll.

240-243 °C (lit.)

Punto di fusione

56-59 °C (lit.)

Stringa SMILE

COc1ccc(N)cc1

InChI

1S/C7H9NO/c1-9-7-4-2-6(8)3-5-7/h2-5H,8H2,1H3
BHAAPTBBJKJZER-UHFFFAOYSA-N

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Applicazioni

p-Anisidine can undergo aerobic oxidation in the presence of gold catalysts to form aromatic azo compounds.
p-Anisidine can be used:
  • In the diastereoselective and enantioselective synthesis of CF3-substituted azoridines catalyzed by a chiral Bronsted acid.
  • To prepare 4-organoselenium-quinolines through multi-component Povarov reaction with ethyl glyoxylate and ethynyl(phenyl)selane, catalyzed by Yb(OTf)3.
  • As a starting material to synthesize 3-fluoro-6-methoxyquinoline in two steps.,
  • To prepare N-PMP protected α-aminopropargylphosphonates by reacting with terminal alkynes and diethyl formylphosphonate hydrate using silver(I) triflate as a catalyst.

Avvertenze

Danger

Indicazioni di pericolo

H300 + H310 + H330,H350,H373,H400

Classi di pericolo

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Carc. 1B - STOT RE 2

Codice della classe di stoccaggio

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

251.6 °F - closed cup

Punto d’infiammabilità (°C)

122 °C - closed cup

Certificati d'analisi (COA)

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