930121

RuCl(p-cymene)[(S,S)-Ts-DPEN]

• Sinonimo/i: [N-[(1S,2S)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]-ruthenium
• Formula empirica (notazione di Hill): C₃₁H₃₅ClN₂O₂RuS
• Numero CAS: 192139-90-5
• Peso molecolare: 636.21
• Numero MDL: MFCD14155881
• Codice UNSPSC: 12352116
• NACRES: NA.21

Proprietà

• Stato: powder or crystals
• Livello qualitativo: 100
• Caratteristiche più verdi: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• Punto di fusione: >175 °C
• Categoria alternativa più verde: Aligned
• Temperatura di conservazione: 2-8°C
• Stringa SMILE: CC(C)c1ccc(C)cc1.Cc2ccc(cc2)S(=O)(=O)N([Ru]Cl)[C@H]([C@@H](N)c3ccccc3)c4ccccc4
• InChI: 1S/C21H21N2O2S.C10H14.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-8(2)10-6-4-9(3)5-7-10;;/h2-15,20-21H,22H2,1H3;4-8H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m0.../s1; AZFNGPAYDKGCRB-XCPIVNJJSA-M

Descrizione

Descrizione generale

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Applicazioni

Catalyst involved in:

• Asymmetric transfer hydrogenation of imines and ketones
• Intramolecular asymmetric reductive amination
• Tandem hydroformylation / hydrogenation of terminal olefins

Reactant involved in studies of thermal decomposition of areneruthenium chiral amido-amine alkyl complexes

RuCl(p-cymene)[(S,S)-Ts-DPEN] is a chiral diamine ligand complexed with ruthenium used for asymmetric hydrogenation reactions.

Informazioni sulla sicurezza

• Codice della classe di stoccaggio: 11 - Combustible Solids
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable