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343706

Sigma-Aldrich

Dichloro(p-cymene)ruthenium(II) dimer

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Sinonimo/i:

(p-Cymene)ruthenium(II) chloride dimer, Benzene, 1-methyl-4-(1-methylethyl)-, ruthenium complex

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About This Item

Formula condensata:
[Ru(p-cymene)Cl2]2
Numero CAS:
52462-29-0
Peso molecolare:
612.39
Numero MDL:
MFCD00064793
Codice UNSPSC:
12161600
ID PubChem:
24861190
NACRES:
NA.22

Impiego in reazioni chimiche

core: ruthenium
reagent type: catalyst
reaction type: C-H Activation

Caratteristiche più verdi

Catalysis
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sustainability

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Punto di fusione

247.0-250.0 °C (dec.) (lit.)

Categoria alternativa più verde

, Aligned

Stringa SMILE

Cl[Ru]Cl.Cl[Ru]Cl.CC(C)c1ccc(C)cc1.CC(C)c2ccc(C)cc2

InChI

1S/2C10H14.4ClH.2Ru/c2*1-8(2)10-6-4-9(3)5-7-10;;;;;;/h2*4-8H,1-3H3;4*1H;;/q;;;;;;2*+2/p-4
LAXRNWSASWOFOT-UHFFFAOYSA-J

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Categorie correlate

Descrizione generale

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Dichloro(p-cymene)ruthenium(II) dimer is a saturated 18-electron complex used as a starting material for the synthesis of organometallic complexes.

Applicazioni

Hydrosilylation Catalysts
Catalyst for greener amine synthesis by reduction of imines with PMHS or hydrogen-borrowing.

A Practical and Benign Synthesis of Primary Amines through Ruthenium-Catalyzed Reduction of Nitriles

Ruthenium-Catalyzed N-Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology
Cyclometalated ruthenium complexes with arylimines and nitrogen-containing heterocycles via C-H bond activation

Pittogrammi

Exclamation mark
GHS07

Avvertenze

Warning

Indicazioni di pericolo

H319

Classi di pericolo

Eye Irrit. 2

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 2

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Certificati d'analisi (COA)

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One-step synthesis of low molecular weight poly (p-phenyleneethynylenevinylene) s via polyaddition of aromatic diynes by catalysis of the [Ru (p-cymene) Cl2] 2/AcOH system
Chiara P et al.
The Journal of Organic Chemistry, 73, 3892-3899 (2008)
Carina Sollert et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(14), 5380-5386 (2015-02-18)
The Ru-catalysed C2-H arylation of indoles and pyrroles by using boronic acids under oxidative conditions is reported. This reaction can be applied to tryptophan derivatives and tolerates a wide range of functional groups on both coupling partners, including bromides and
Bin Li et al.
Dalton transactions (Cambridge, England : 2003), 41(36), 10934-10937 (2012-08-15)
The reaction of [RuCl(2)(p-cymene)](2) with arylimines and 4 equiv. of KOAc in methanol at room temperature produces stable (N^C)-cyclometallated ruthenium(II) complexes via C-H bond activation/deprotonation. This method can be applied also to nitrogen-containing molecules: N-phenylpyrazole, 2-phenyl-2-oxazoline and benzo[h]quinoline. N-Phenyl-pyrazole, [RuCl(2)(p-cymene)](2)

Articoli

Hydrosilylation Catalyst

Trost group's protocol yields α-vinylsilanes from terminal acetylenes using [Cp*Ru(MeCN)3]PF6 catalyst and others for hydrosilylation.

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