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Documenti fondamentali

511609

Sigma-Aldrich

Aluminum-tri-sec-butoxide

99.99% trace metals basis

Sinonimo/i:

Aluminum sec-butoxide

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About This Item

Formula condensata:
Al[OCH(CH3)C2H5]3
Numero CAS:
Peso molecolare:
246.32
Beilstein:
3910908
Numero CE:
Numero MDL:
Codice UNSPSC:
12352103
ID PubChem:
NACRES:
NA.23

Saggio

99.99% trace metals basis

Stato

liquid

Temp. autoaccensione

763 °F

Limite di esplosione

9.8 %

Impiego in reazioni chimiche

core: aluminum

P. ebollizione

200-206 °C/30 mmHg (lit.)

Densità

0.967 g/mL at 25 °C (lit.)

Stringa SMILE

CCC(C)O[Al](OC(C)CC)OC(C)CC

InChI

1S/3C4H9O.Al/c3*1-3-4(2)5;/h3*4H,3H2,1-2H3;/q3*-1;+3
WOZZOSDBXABUFO-UHFFFAOYSA-N

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Caratteristiche e vantaggi

Has been utilized in making high-surface-area alumina using 2,4-pentanedione (Aldrich product P775-4) as a chelating agent.

Pittogrammi

FlameSkull and crossbones

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Flam. Liq. 3

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

78.8 °F - closed cup

Punto d’infiammabilità (°C)

26 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Megan D Reeves et al.
Biophysical chemistry, 128(1), 13-18 (2007-03-21)
Differential scanning calorimetry and (31)P-NMR were used to study the effects of butanol isomers on the thermotropic phase behavior of dipalmitoylphosphatidylcholine (DPPC) bilayers. The threshold concentration for the onset of interdigitation for each isomer was determined by the disappearance of
R A Rosenberg et al.
Physical review letters, 101(17), 178301-178301 (2008-11-13)
We demonstrate for the first time that low-energy spin-polarized secondary electrons, produced by irradiation of a magnetic substrate, can induce chiral-selective chemistry. Our approach was to perform detailed measurements of the reaction rate for x-ray induced, secondary electron photolysis of
Fengli Yang et al.
Chemical communications (Cambridge, England), 47(15), 4469-4471 (2011-03-04)
A new solid acid, based on tantalum hydroxide, was used to catalyze saccharide dehydration into 5-hydroxymethylfurfural (HMF) with high catalytic activity and excellent stability in a water-2-butanol biphasic system. Furthermore, good results were also obtained from Jerusalem artichoke juice with
Ravi K Pathak et al.
Environmental science & technology, 46(21), 11660-11669 (2012-09-19)
Limonene has a strong tendency to form secondary organic aerosol (SOA) in the atmosphere and in indoor environments. Initial oxidation occurs mainly via ozone or OH radical chemistry. We studied the effect of O(3) concentrations with or without a OH
Hirofumi Sonoda et al.
The Journal of biological chemistry, 282(47), 34085-34092 (2007-09-28)
Although organelles such as the endoplasmic reticulum and Golgi apparatus are highly compartmentalized, these organelles are interconnected through a network of vesicular trafficking. The marine sponge metabolite ilimaquinone (IQ) is known to induce Golgi membrane fragmentation and is widely used

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