381322
4,4′-Difluorobenzil
98%
Autenticatiper visualizzare i prezzi riservati alla tua organizzazione & contrattuali
About This Item
Formula condensata:
FC6H4COCOC6H4F
Numero CAS:
Peso molecolare:
246.21
Numero MDL:
Codice UNSPSC:
12352100
ID PubChem:
Prodotti consigliati
Saggio
98%
Punto di fusione
120-122 °C (lit.)
Stringa SMILE
Fc1ccc(cc1)C(=O)C(=O)c2ccc(F)cc2
InChI
1S/C14H8F2O2/c15-11-5-1-9(2-6-11)13(17)14(18)10-3-7-12(16)8-4-10/h1-8H
BRKULQOUSCHDGS-UHFFFAOYSA-N
Informazioni sul gene
human ... ACHE(43) , BCHE(590) , CES1(1066)
Descrizione generale
4,4′-Difluorobenzil is a benzil derivative. Its reaction with benzylurea and phenethylurea has been investigated. It is reported to undergo condensation with Fe2(SH)2(CO)6 to afford the adduct Fe2[S2C2(OH)2(C6H4-4-F)2](CO)6.
Applicazioni
4,4′-Difluorobenzil is suitable for use in the preparation of 2,3-bis(4-fluorophenyl)thieno[3,4-b]pyrazine. It may be used in the synthesis of following:
- poly(ether-α-diketone)s, via nucleophilic substitution reaction with bisphenol A
- 4,4′-difluoro-2,3-diphenylpyrazine (DPPF) and 4,4′-difluoro-5-methyl 2,3-diphenylpyrazine (MDPPF), via direct condensation with ethylenediamine and 1,2-diaminopropane, respectively
- 2,3-bis(4-fluorophenyl)quinoxaline, via direct condensation with 1,2-phenylenediamine
Avvertenze
Warning
Indicazioni di pericolo
Consigli di prudenza
Classi di pericolo
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Organi bersaglio
Respiratory system
Codice della classe di stoccaggio
11 - Combustible Solids
Classe di pericolosità dell'acqua (WGK)
WGK 3
Punto d’infiammabilità (°F)
Not applicable
Punto d’infiammabilità (°C)
Not applicable
Dispositivi di protezione individuale
dust mask type N95 (US), Eyeshields, Gloves
Scegli una delle versioni più recenti:
Possiedi già questo prodotto?
I documenti relativi ai prodotti acquistati recentemente sono disponibili nell’Archivio dei documenti.
Jane L Stanley et al.
Organometallics, 26(8), 1907-1911 (2008-07-02)
Reaction of Fe(2)(SH)(2)(CO)(6) and HCHO, which gives Fe(2)[(SCH(2))(2)NH](CO)(6) in the presence of NH(3), affords the possible intermediate Fe(2)(SCH(2)OH)(2)(CO)(6), which has been characterized crystallographically as its axial-equatorial isomer. Fe(2)(SCH(2)OH)(2)(CO)(6) was shown to react with ammonia and amines to give Fe(2)[(SCH(2))(2)NR](CO)(6) (R
Giulio G Muccioli et al.
Organic letters, 5(20), 3599-3602 (2003-09-26)
[reaction: see text] A new access to benzhydryl-phenylureas is described. These new interesting urea derivatives were obtained by reaction of substituted benzils with substituted phenylureas under microwave irradiation. Phenylthiourea, when reacted with benzil, gave 3-phenyl-thiohydantoin. Moreover, benzylurea, as phenethylurea, gave
Synthesis and Characterization of N-(2-Ethylhexyl) carbazole-2, 3-Bis (4-fluorophenyl)) thieno [3, 4-b] pyrazine Copolymer.
Li JC, et al.
Bull. Korean Chem. Soc., 31(7), 2073-2076 (2010)
Yellow organic light-emitting diodes based on phosphorescent iridium (III) pyrazine complexes: Fine tuning of emission color.
Ge G, et al.
Inorgorganica Chimica Acta, 362(7), 2231-2226 (2009)
Fu-Ming Hwang et al.
Inorganic chemistry, 44(5), 1344-1353 (2005-03-01)
Rational design and syntheses of four iridium complexes (1-4) bearing two substituted quinoxalines and an additional 5-(2-pyridyl) pyrazolate or triazolate as the third coordinating ligand are reported. Single-crystal X-ray diffraction studies of 1 reveal a distorted octahedral geometry, in which
Il team dei nostri ricercatori vanta grande esperienza in tutte le aree della ricerca quali Life Science, scienza dei materiali, sintesi chimica, cromatografia, discipline analitiche, ecc..
Contatta l'Assistenza Tecnica.