374377

2-(Triphenylphosphoranylidene)propionaldehyde

98%

• Sinonimo/i: 1-Formylethylidenetriphenylphosphorane
• Formula condensata: (C₆H₅)₃P=C(CH₃)CHO
• Numero CAS: 24720-64-7
• Peso molecolare: 318.35
• Numero MDL: MFCD00075596
• Codice UNSPSC: 12352114
• ID PubChem: 24863304
• NACRES: NA.22

Proprietà

• Livello qualitativo: 100
• Saggio: 98%
• Stato: powder
• Impiego in reazioni chimiche: reaction type: C-C Bond Formation
• Punto di fusione: 219-221 °C (lit.)
• Gruppo funzionale: aldehyde; phosphine
• Stringa SMILE: CC(C=O)=P(c1ccccc1)(c2ccccc2)c3ccccc3
• InChI: 1S/C21H19OP/c1-18(17-22)23(19-11-5-2-6-12-19,20-13-7-3-8-14-20)21-15-9-4-10-16-21/h2-17H,1H3; VHUQEFAWBCDBSC-UHFFFAOYSA-N

Descrizione

Applicazioni

Reactant for:

• Preparation of acitretin analogs with antitumor activity
• Stereoselective synthesis of essential building blocks of phorboxazole A via hetero Diels-Alder and stereoselective hetero-Michael addition/equilibration
• Preparation of C1-C14 fragment of sarcoglaucol-16-one via Z-selective ando-type Horner-Wadsworth-Emmons olefination
• Wittig reactions
• Synthesis of ring-expanded and epothilone-hybridized macrosphelide analogs as apoptosis-inducing agents
• Preparation of phosphonic acid-containing analogs of mycophenolic acid as inhibitors of IMPDH

Informazioni sulla sicurezza

• Codice della classe di stoccaggio: 11 - Combustible Solids
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable
• Dispositivi di protezione individuale: Eyeshields, Gloves, type N95 (US)