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307882

Sigma-Aldrich

(R)-(−)-2-Phenylglycine methyl ester hydrochloride

≥95%

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About This Item

Formula condensata:
C6H5CH(NH2)CO2CH3·HCl
Numero CAS:
19883-41-1
Peso molecolare:
201.65
Numero CE:
243-399-9
Numero MDL:
MFCD00137487
Codice UNSPSC:
12352200
eCl@ss:
32160406
ID PubChem:
24858635
NACRES:
NA.22

Saggio

≥95%

Forma fisica

solid

Attività ottica

[α]20/D −118°, c = 1 in H2O

Impiego in reazioni chimiche

reaction type: solution phase peptide synthesis

Punto di fusione

189-191 °C (lit.)

applicazioni

peptide synthesis

Stringa SMILE

Cl.COC(=O)[C@H](N)c1ccccc1

InChI

1S/C9H11NO2.ClH/c1-12-9(11)8(10)7-5-3-2-4-6-7;/h2-6,8H,10H2,1H3;1H/t8-;/m1./s1
DTHMTBUWTGVEFG-DDWIOCJRSA-N

Pittogrammi

Exclamation mark
GHS07

Avvertenze

Warning

Indicazioni di pericolo

H319

Consigli di prudenza

P305 + P351 + P338

Classi di pericolo

Eye Irrit. 2

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

dust mask type N95 (US), Eyeshields, Gloves

Certificati d'analisi (COA)

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Sigma-Aldrich

76427

Penicillin Amidase from Escherichia coli

Wei Du et al.
Sheng wu gong cheng xue bao = Chinese journal of biotechnology, 18(2), 242-245 (2002-08-01)
A novel reaction-enzymatic ammonolysis discovered in the mid of 1990s has been demonstrated to be a very promising alternative in the preparation of optically pure compounds. The effects of organic solvent, initial water activity, temperature and additives on lipase Novozym435-catalyzed
Alessandro Moretto et al.
Chirality, 17(8), 481-487 (2005-08-23)
Reactions of a racemic amine with chiral, N(alpha)-acetylated, C(alpha)-methyl l-phenylglycine-based dipeptide 5(4H)-oxazolones proceed diastereoselectively to give predominantly dipeptide alkylamides comprising d-alpha-phenylethylamine. Diastereoselectivity is remarkably sensitive to solvent polarity and reaction temperature but not significantly to the nature of the C(alpha)-tetrasubstituted
John W Van Klink et al.
Chirality, 16(8), 549-558 (2004-08-04)
Several Anisotome diterpene derivatives were synthesized in an attempt to obtain a crystalline compound for X-ray analysis. Although we were unable to obtain a suitable crystal, the absolute configuration of the irregular diterpene skeleton was determined using two other techniques:
Wei Du et al.
Biotechnology and applied biochemistry, 38(Pt 2), 107-110 (2003-05-17)
Ammonium, provided by ammonium carbamate as a novel acyl acceptor, was adopted for enzymic enantioselective ammonolysis of racemic phenylglycine methyl ester in this paper and it has been found that the reaction conditions have profound effects on enzymic activity and
R Fernández-Lafuente et al.
Biomacromolecules, 2(1), 95-104 (2001-12-26)
The importance of the stabilization of the quaternary structure of multimeric enzymes has been illustrated using a model reaction with great industrial relevance: the enzymatic synthesis of ampicillin from 6-amino penicillanic acid (6APA) and phenylglycine methyl ester (PGM) catalyzed by
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