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302937

Sigma-Aldrich

Perfluoro(methylcyclohexane)

technical grade, 90%

Sinonimo/i:

(Trifluoromethyl)undecafluorocyclohexane, Perfluoromethylcyclohexane

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60,30 €
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164,00 €

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25 G
60,30 €
100 G
164,00 €

About This Item

Formula condensata:
C6F11CF3
Numero CAS:
355-02-2
Peso molecolare:
350.05
Beilstein:
1915981
Numero CE:
206-573-5
Numero MDL:
MFCD00001468
Codice UNSPSC:
12352100
ID PubChem:
24858283
NACRES:
NA.22

60,30 €

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Grado

technical grade

Livello qualitativo

100

Saggio

90%

Stato

liquid

Indice di rifrazione

n17/D 1.285 (lit.)

P. ebollizione

76 °C (lit.)

Densità

1.787 g/mL at 25 °C (lit.)

Gruppo funzionale

fluoro

Stringa SMILE

FC(F)(F)C1(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C1(F)F

InChI

1S/C7F14/c8-1(7(19,20)21)2(9,10)4(13,14)6(17,18)5(15,16)3(1,11)12
QIROQPWSJUXOJC-UHFFFAOYSA-N

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Categorie correlate

Descrizione generale

Mixtures of chloroform and perfluoro(methylcyclohexane) can be used as solvents for "fluorous" biphase reactions.[1] Gas-phase structure of perfluoro(methylcyclohexane) was investigated.[2]

Applicazioni

Perfluoro(methylcyclohexane) can be used as:
  • A reactant to synthesize perfluoro-2-methylcyclohex-1-enolate by photochemical reaction with tetrabutylammonium iodide in water.[3]
  • A fluorous solvent to synthesize polynorbornene via ring-opening metathesis polymerization (ROMP) of norbornene using fluorous Grubbs′ second-generation catalyst.[4]

It can also be used as a solvent to investigate fluorophilicity of a series of hydrocarbon and fluorocarbon-functionalized nicotinic acid esters.[5]
Perfluoro(methylcyclohexane) was employed as solvent to investigate fluorophilicity of a series of hydrocarbon and fluorocarbon-functionalized nicotinic acid esters.[5]

Codice della classe di stoccaggio

10 - Combustible liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Eyeshields, Gloves

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Certificati d'analisi (COA)

Lot/Batch Number
BCCM2870
BCCK6779
BCCJ9387
BCCH4692
BCCG9941

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Mei-Jy Jeng et al.
Critical care medicine, 34(4), 1099-1105 (2006-02-18)
To investigate the therapeutic effects of bronchoalveolar lavage (BAL) with either diluted surfactant (SBAL) or perfluorochemical liquid (PBAL), followed by either conventional mechanical ventilation (CMV) or partial liquid ventilation (PLV), on lung injury and proinflammatory cytokine production induced by meconium
Stephanie S Adkins et al.
The journal of physical chemistry. B, 112(15), 4760-4769 (2008-03-28)
The technique of hydrophobic ion pairing was used to solubilize the lipase from Candida rugosa in a fluorinated solvent, perfluoromethylcyclohexane (PFMC), in complex with a perfluoropolyether (PFPE) surfactant, KDP 4606. The enzyme-surfactant complex was determined to have a hydrodynamic diameter
Development of Highly Active Ring Opening Metathesis Polymerization Catalyst Systems-A New Approach for Green Catalyst Design
Tuba R, et al.
Proceedings, 2011(1), EVO3-EVO3 (2011)
Functionalization of saturated fluorocarbons with and without light
Chen X and Lemal DM
Journal of Fluorine Chemistry, 127(9), 1158-1167 (2006)
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Ultrasonics sonochemistry, 54, 250-255 (2019-02-05)
We have developed a new emulsion template method for the synthesis of poly(methylmethacrylate) (PMMA) hollow nanoparticles with different sizes. This synthetic method involves sequential ultrasonic irradiation (20 kHz → 500 kHz → 1.6 MHz → 2.4 MHz → 5.0 MHz) for acoustic emulsification of a water-insoluble fluorous solvent such as perfluoromethylcyclohexane (PFMCH) in
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