295337
Trifluoromethane
≥98%
Sinonimo/i:
Fluoroform, HFC-23
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About This Item
Formula condensata:
CHF3
Numero CAS:
Peso molecolare:
70.01
Numero CE:
Numero MDL:
Codice UNSPSC:
12142100
ID PubChem:
NACRES:
NA.22
Prodotti consigliati
Densità del vapore
2.43 (vs air)
Tensione di vapore
635 psi ( 21 °C)
Saggio
≥98%
P. ebollizione
−84 °C (lit.)
Punto di fusione
−160 °C (lit.)
Stringa SMILE
FC(F)F
InChI
1S/CHF3/c2-1(3)4/h1H
XPDWGBQVDMORPB-UHFFFAOYSA-N
Confezionamento
Supplied in a carbon steel lecture bottle with a CGA180M/CGA110F needle valve installed.
Compatible with the following:
Compatible with the following:
- Aldrich® lecture-bottle station systems
- Aldrich® lecture-bottle gas regulators
Altre note
See Technical Information Bulletin AL-151 Gas Regulators: Selection, Installation, and Operation
Note legali
Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
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Raccomandato
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Regolatore
Valvola di controllo
Valvola di spurgo
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Avvertenze
Warning
Indicazioni di pericolo
Consigli di prudenza
Classi di pericolo
Press. Gas Liquefied gas
Codice della classe di stoccaggio
2A - Gases
Classe di pericolosità dell'acqua (WGK)
WGK 1
Punto d’infiammabilità (°F)
Not applicable
Punto d’infiammabilità (°C)
Not applicable
Dispositivi di protezione individuale
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
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Mark A Honey et al.
The Journal of organic chemistry, 77(3), 1396-1405 (2012-01-24)
Ethyl 2-diazo-4,4,4-trifluoro-3-oxobutanoate is a highly versatile intermediate for the synthesis of a wide range of trifluoromethyl heterocycles. With the use of rhodium(II) or copper(II) catalyzed carbene X-H insertion reactions as key steps, a diverse set of trifluoromethyl-oxazoles, -thiazoles, -imidazoles, -1,2,4-triazines
Charles S Thomoson et al.
The Journal of organic chemistry, 78(17), 8904-8908 (2013-08-13)
Fluoroform, CHF3, a non-ozone-depleting, nontoxic, and inexpensive gas can be used as a difluorocarbene source in a process for the conversion of phenols and thiophenols to their difluoromethoxy and difluorothiomethoxy derivatives. The reactions are carried out at moderate temperatures and
Yongwei Wu et al.
Journal of the American Chemical Society, 134(35), 14334-14337 (2012-08-22)
A new approach toward the asymmetric synthesis of optically active trifluoromethylated amines was enabled by an unprecedented, highly enantioselective catalytic isomerization of trifluoromethyl imines with a new chiral organic catalyst. Not only aryl but also alkyl trifluoromethylated amines could be
Shun Noritake et al.
Organic & biomolecular chemistry, 7(17), 3599-3604 (2009-08-14)
Chiral nonracemic guanidines act as Brønsted bases to generate guanidinium enolates for the enantioselective electrophilic trifluoromethylation of beta-keto esters by means of S-(trifluoromethyl)dibenzothiophenium tetrafluoroborate (Umemoto reagent) with good enantioselectivity of 60-70% range. Despite the fact that the ees are still
Thierry Milcent et al.
Organic & biomolecular chemistry, 8(13), 3025-3030 (2010-05-12)
Trifluoromethyl nitrones were obtained in high yields by condensation of various hydroxylamines with trifluoroacetaldehyde hydrate. The nucleophilic diastereoselective additions of organometallic reagents to these nitrones afforded the corresponding optically active trifluoroethyl hydroxylamines in good yields.
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