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242306

Sigma-Aldrich

Allyl chloroformate

97%, for peptide synthesis

Sinonimo/i:

2-Propen-1-yl chloroformate, Allyloxycarbonyl chloride

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47,50 €
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5 G
47,50 €
100 G
173,00 €

About This Item

Formula condensata:
ClCOOCH2CH=CH2
Numero CAS:
2937-50-0
Peso molecolare:
120.53
Beilstein:
773915
Numero CE:
220-916-6
Numero MDL:
MFCD00000648
Codice UNSPSC:
12190000
ID PubChem:
24854549
NACRES:
NA.22

47,50 €

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Nome del prodotto

Allyl chloroformate, 97%

Tensione di vapore

3.67 psi ( 20 °C)

Saggio

97%

Stato

liquid

Indice di rifrazione

n20/D 1.422 (lit.)

P. ebollizione

~27 °C/11 mmHg (lit.)

Densità

1.134 g/mL at 20 °C (lit.)

applicazioni

peptide synthesis

Temperatura di conservazione

−20°C

Stringa SMILE

ClC(=O)OCC=C

InChI

1S/C4H5ClO2/c1-2-3-7-4(5)6/h2H,1,3H2
CAEWJEXPFKNBQL-UHFFFAOYSA-N

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Categorie correlate

Descrizione generale

Allyl chloroformate is an organic compound used to synthesize numerous compounds like allyl carbamates and allyl carbonates. Additionally, it can be used for the preparation of α-allyl carbonyls and α, β-unsaturated carbonyls.[1]

Applicazioni

Allyl chloroformate is used in the synthesis of:
  • Histones and their analogs.[2]
  • Alloc-TL monomer (N-(allyloxy)carbonylhomocysteine thiolactone) from cyclic thioester (d,l-homocysteine thiolactonehydrochloride).[3]

Avvertenze

Danger

Indicazioni di pericolo

H226,H301,H314,H330

Classi di pericolo

Acute Tox. 1 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 3 - Skin Corr. 1B

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

87.8 °F - closed cup

Punto d’infiammabilità (°C)

31 °C - closed cup

Dispositivi di protezione individuale

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificati d'analisi (COA)

Lot/Batch Number
SHBP4647
SHBN5915
SHBN4259
SHBN2550
SHBM4450

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Over the past years, significant effort has been dedicated to synthesizing low-shrinking formulations, however, development of dental composites with low volumetric shrinkage continues to be challenging. The purpose of this study was to synthesize a bisphenol allylic derivate (BPhADAC) and
Palladium-catalyzed synthesis of substituted cycloheptane-1,4-diones by an asymmetric ring-expanding allylation (AREA).
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[Toxic action of allylchloroformate].
E F Oskerko et al.
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Degradation of clofarabine (3) in 0.9% saline solution at 100 degrees C afforded three degradation products which were determined to be formamidopyrimidines 4-6. Compounds 4 and 5 were assigned as C(1') anomers on the basis of one-dimensional and two-dimensional NMR
Total chemical synthesis of histones and their analogs, assisted by native chemical ligation and palladium complexes
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Domande

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 risposta

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Utile?

  2. How can I determine the shelf life / expiration / retest date of this product?

    1 risposta

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Utile?

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