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179906

Sigma-Aldrich

Tributylborane solution

1.0 M in THF

Sinonimo/i:

TBB, Tributylboron

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About This Item

Formula condensata:
[CH3(CH2)3]3B
Numero CAS:
122-56-5
Peso molecolare:
182.15
Numero MDL:
MFCD00009423
Codice UNSPSC:
12352001
ID PubChem:
24850833

Stato

liquid

Impiego in reazioni chimiche

reagent type: reductant

Concentrazione

1.0 M in THF

Densità

0.834 g/mL at 25 °C

Stringa SMILE

CCCCB(CCCC)CCCC

InChI

1S/C12H27B/c1-4-7-10-13(11-8-5-2)12-9-6-3/h4-12H2,1-3H3
CMHHITPYCHHOGT-UHFFFAOYSA-N

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Applicazioni

Reactant for:
  • Addition reactions for synthesis of phenyltrialkylborate salts
  • Boron-based multicomponent reactions for generation of substituted aziridines, oxazolidines, and pyrrolidines
  • Suzuki-Miyaura cross coupling of halopurines with trialkylboranes for the synthesis of adenosine A2A receptor antagonists
  • Multicomponent C-alkylation reactions with aromatic aldimines
  • One-pot alkylation-boration and electrophilic substitution

Avvertenze

Danger

Indicazioni di pericolo

H225,H302,H314,H335,H336,H351

Classi di pericolo

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

Organi bersaglio

Central nervous system, Respiratory system

Rischi supp

EUH019

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 1

Punto d’infiammabilità (°F)

1.4 °F

Punto d’infiammabilità (°C)

-17 °C

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Certificati d'analisi (COA)

Lot/Batch Number
SHBK6600
SHBG2799V
SHBB4583
13619HH
19012JQ

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