Passa al contenuto
Merck
Tutte le immagini(1)

Documenti fondamentali

Visualizza tutta la documentazione

157457

Sigma-Aldrich

3,5-Di-tert-butyl-o-benzoquinone

98%

Sinonimo/i:

3,5-Bis(1,1-dimethylethyl)-3,5-cyclohexadiene-1,2-dione, 3,5-Di-t-butyl-o-quinone, 3,5-Di-tert-butyl-1,2-benzoquinone, 3,5-Di-tert-butyl-o-quinone, 3,5-Di-tert-butylcyclohexa-3,5-diene-1,2-dione, 3,5-Di-tert-butylquinone, 3,5-Ditert-butylcyclohexa-3,5-diene-1,2-dione, 4,6-Di-tert-butyl-1,2-benzoquinone, 4,6-Di-tert-butyl-o-benzoquinone

Autenticatiper visualizzare i prezzi riservati alla tua organizzazione & contrattuali

Scegli un formato

10 G
204,00 €

204,00 €

Per informazioni sulla disponibilità, contatta il Servizio Clienti.
Richiedi un ordine bulk
Tutte le immagini(1)

Scegli un formato

Cambia visualizzazione
10 G
204,00 €

About This Item

Formula condensata:
[(CH3)3C]2C6H2(=O)2
Numero CAS:
3383-21-9
Peso molecolare:
220.31
Beilstein:
2047944
Numero CE:
222-189-0
Numero MDL:
MFCD00001647
Codice UNSPSC:
12352100
ID PubChem:
24849680
NACRES:
NA.22

204,00 €

Per informazioni sulla disponibilità, contatta il Servizio Clienti.
Richiedi un ordine bulk

Livello qualitativo

100

Saggio

98%

Stato

solid

Punto di fusione

112-114 °C (lit.)

Stringa SMILE

CC(C)(C)C1=CC(=O)C(=O)C(=C1)C(C)(C)C

InChI

1S/C14H20O2/c1-13(2,3)9-7-10(14(4,5)6)12(16)11(15)8-9/h7-8H,1-6H3
NOUZOVBGCDDMSX-UHFFFAOYSA-N

Informazioni sul gene

human ... ACHE(43) , BCHE(590) , CES1(1066)

Cerchi prodotti simili? Visita Guida al confronto tra prodotti

Categorie correlate

Descrizione generale

Reactions of the phosphinidene-bridged complexes [Fe2(η5-C5H5)2(μ-PR)(μ-CO)(CO)2] (R = Cy, Ph) with 3,5-di-tert-butyl-o-benzoquinone has been reported.[1]

Applicazioni

3,5-Di-tert-butyl-o-benzoquinone was used in the preparation of benzoxazoles derivative ligands.[2] It was also used in the preparation of 1,4-benzodioxines via hetero Diels Alder reaction with acyclic dienes.[3]

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Eyeshields, Gloves, type N95 (US)

Scegli una delle versioni più recenti:

Certificati d'analisi (COA)

Lot/Batch Number
0000243793
0000246708
0000234429
MKCG5074
MKBW8205V

Non trovi la versione di tuo interesse?

Se hai bisogno di una versione specifica, puoi cercare il certificato tramite il numero di lotto.

Cerca un COA

Possiedi già questo prodotto?

I documenti relativi ai prodotti acquistati recentemente sono disponibili nell’Archivio dei documenti.

Visita l’Archivio dei documenti

I clienti hanno visto anche

Slide 1 of 5

1 of 5

4-tert-Butylcatechol ≥99.0%

Sigma-Aldrich

19671

4-tert-Butylcatechol

2,6-Dimethoxy-1,4-benzoquinone 97%

Sigma-Aldrich

428566

2,6-Dimethoxy-1,4-benzoquinone

9,10-Phenanthrenequinone 95%

Sigma-Aldrich

275034

9,10-Phenanthrenequinone

Duroquinone 97%

Sigma-Aldrich

D223204

Duroquinone

2,5-Dimethyl-1,4-benzoquinone ≥98.0%

Sigma-Aldrich

39579

2,5-Dimethyl-1,4-benzoquinone

M Angeles Alvarez et al.
Dalton transactions (Cambridge, England : 2003), 41(48), 14498-14513 (2012-10-12)
The title complexes reacted readily with the methylating agents MeI and CF(3)SO(3)Me, chalcogens (O(2), S(8)) and borane adducts BH(3)·L (L = THF, N(t)Bu(3), PPh(3)) to initially give the corresponding neutral or cationic derivatives of the type [Fe(2)Cp(2){μ-P(E)R}(μ-CO)(CO)(2)](n) (Cp = η(5)-C(5)H(5);
Hitomi Tanaka et al.
International journal of molecular sciences, 19(10) (2018-09-27)
It is generally considered that eumelanin (EM) is photoprotective while pheomelanin (PM) is phototoxic. A recent study using a mouse model demonstrated that PM produces reactive oxygen species (ROS) that cause DNA damage and eventually lead to melanomagenesis. A biochemical
Norma A Macías-Ruvalcaba et al.
The journal of physical chemistry. B, 110(43), 22043-22047 (2006-10-27)
The electrochemical reduction of 3,5-di-tert-butyl-1,2-benzoquinone, 1, has been studied in acetonitrile with added 2,2,2-trifluoroethanol, 2. At low concentrations of 2 the reaction proceeds by the following pathway: reduction of the quinone (Q) to its anion radical (Q*-) followed by complexation
Hetero Diels-Alder reactions of 3, 5-di-tert-butyl-o-benzoquinone with acyclic dienes: novel synthesis of 1, 4-benzodioxines.
Nair V and Kumar S.
Journal of the Chemical Society. Chemical Communications, 11, 1341-1342 (1994)
Olga Iasco et al.
Inorganic chemistry, 51(4), 2588-2596 (2012-01-12)
Two benzoxazoles derivative ligands were synthesized from the condensation of 3,5-di-tert-butyl-o-benzoquinone (DTBBQ) with ethanolamine or 1,3-diamino-2-hydroxypropane in methanol. Condensation of DTBBQ with ethanolamine gives the expected 5,7-di-tert-butyl-2-methylenhydroxylbenzoxazole (HL1) while with 1,3-diamino-2-hydroxypropane it gives (2-hydroxyethyl-2-{2,4-bis(1,1-dimethylethyl)-1-phenol-6 amino}-2{5,7-di-tert-butyl-benzoxazole}) (H(2)L2) with only one benzoxazole
Visualizza tutti i documenti correlati

Domande

Recensioni

Nessuna valutazione

Filtri attivi

Il team dei nostri ricercatori vanta grande esperienza in tutte le aree della ricerca quali Life Science, scienza dei materiali, sintesi chimica, cromatografia, discipline analitiche, ecc..

Contatta l'Assistenza Tecnica.