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Merck

60832

Sigma-Aldrich

硝酸钴(II) 六水合物

puriss. p.a., ACS reagent, Ni ≤0.001%, ≥99.0% (KT)

别名:

硝酸亚钴, 硝酸亚钴 六水合物, 硝酸,钴(II)盐

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About This Item

线性分子式:
Co(NO3)2 · 6H2O
CAS号:
分子量:
291.03
MDL號碼:
分類程式碼代碼:
12352300
PubChem物質ID:
NACRES:
NB.24

等級

ACS reagent
puriss. p.a.

化驗

≥99.0% (KT)

形狀

powder or crystals

反應適用性

reagent type: catalyst
core: cobalt

pH值

4 (20 °C, 100 g/L)

mp

55 °C (lit.)

負離子痕跡

chloride (Cl-): ≤10 mg/kg
sulfate (SO42-): ≤50 mg/kg

正離子痕跡

Ca: ≤10 mg/kg
Cd: ≤10 mg/kg
Cr: ≤50 mg/kg
Cu: ≤10 mg/kg
Fe: ≤10 mg/kg
K: ≤100 mg/kg
Mg: ≤10 mg/kg
Mn: ≤20 mg/kg
NH4+: ≤500 mg/kg
Na: ≤100 mg/kg
Ni: ≤10 mg/kg
Pb: ≤10 mg/kg
Zn: ≤50 mg/kg

SMILES 字串

O.O.O.O.O.O.[Co++].[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/Co.2NO3.6H2O/c;2*2-1(3)4;;;;;;/h;;;6*1H2/q+2;2*-1;;;;;;

InChI 密鑰

QGUAJWGNOXCYJF-UHFFFAOYSA-N

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一般說明

六水合硝酸钴(II)(Co(NO32·6H2O)是水合钴盐。已经对它的逐步热降解进行了研究。它提供无水硝酸钴(II)作为分解产物。

應用

硝酸钴(II)六水合物可用于制备以下配合物(bz =苯并咪唑,abz =阿苯达唑,ntb =三(2-苯并咪唑基甲基)胺,2ab = 2-氨基苯并咪唑):
  • 二硝基 - (三苯基胂氧化物)-钴(II)络合物
  • [Co(bz)2(NO3)2].0.5EtOH
  • [Co(abz)2(NO3)2].2.5H2O
  • [Co(ntb)NO3]NO3.H2O

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B Inhalation - Eye Dam. 1 - Muta. 2 - Ox. Sol. 2 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 2 Inhalation

標靶器官

Lungs

儲存類別代碼

5.1B - Oxidizing hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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Some Phosphine Oxide and Arsine Oxide Complexes of Cobalt (II) Nitrate.
Cotton FA, et al.
Inorganic Chemistry, 2(6), 1162-1165 (1963)
Horacio López-Sandoval et al.
Journal of inorganic biochemistry, 102(5-6), 1267-1276 (2008-02-29)
In this work we present the synthesis, structural and spectroscopic characterisation of a series of cobalt(II) and zinc(II) coordination compounds with benzimidazole (bz) and its 2-benzimidazole derivatives: 2-aminobenzimidazole (2ab), albendazole (abz) and tris(2-benzimidazolylmethyl)amine (ntb). The compounds were evaluated for their
Thermal decomposition of cobalt nitrato compounds: Preparation of anhydrous cobalt (II) nitrate and its characterisation by Infrared and Raman spectra.
Ehrhardt C, et al.
Thermochimica Acta, 432(1), 36-40 (2005)
Massimiliano Aschi et al.
Journal of mass spectrometry : JMS, 44(7), 1038-1046 (2009-04-01)
The nature of the ionic species, formed by electrospray ionization (ESI) of Co(NO3)2/CH3OH solutions with a pair of aminoalcohols W and Y, has been investigated by mass spectrometric and computational methods. Collision induced dissociation (CID) of ions, formally corresponding to
William Buchmann et al.
Journal of mass spectrometry : JMS, 42(4), 517-526 (2007-02-27)
The electronebulization of a cobalt(II)/cysteine(Cys) mixture in water/methanol (50/50) produced mainly cobalt-cationized species. Three main groups of the Co-cationized species can be distinguished in the ESI-MS spectrum: (1) the cobalt complexes including the cysteine amino acid only (they can be

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